trans-{Mn(CO)4(PPh3)2} trifluoromethanesulfonate | 111635-47-3

• 英文名称: trans-{Mn(CO)4(PPh3)2} trifluoromethanesulfonate
• CAS: 111635-47-3
• 化学式: CF₃O₃S*C₄₀H₃₀MnO₄P₂
• 分子量: 840.632
• InChiKey: JHPKKLZENNINHM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  mer,trans-Mn(CO)3(PPh3)2CHO 、 三氟甲烷磺酸甲酯 以 二氯甲烷 为溶剂， 以78%的产率得到methoxymethyl mer,trans-Mn(CO)3(PPh3)2
  参考文献：
  名称：

  由金属甲酰基合成烷氧基甲基络合物

  摘要：

  Syntheses of seven alkoxymethyl complexes, M-CH2OR (R = Me, Et), from the corresponding metal formyls are described; the metals are manganese (compounds 1a-b, 2, and 3), rhenium (compounds 4 and 5), or molybdenum (compound 6). Four of these (1b and 3-5) are new compounds; the details of the syntheses of the other three have not been reported previously. Examples are given of three distinct synthetic routes; all routes require initiation by the action of an electrophile on the metal formyl complex. Variations in the procedures are dictated by the reactivity of the formyl complex and that of its protonated or alkylated form.

  DOI：

  10.1021/om00050a065

文献信息

• Reactions of manganese formyl complexes with electrophiles
  作者：Dorothy H. Gibson、Santosh K. Mandal、Kathryn Owens、John F. Richardson

  DOI：10.1021/om00155a037

  日期：1987.12