[3,6-di(dimethyliminio)-1,2,4,5-tetrathian]CoBr4 | 320774-42-3

• 英文名称: [3,6-di(dimethyliminio)-1,2,4,5-tetrathian]CoBr4
• CAS: 320774-42-3
• 化学式: Br₄Co*C₆H₁₂N₂S₄
• 分子量: 619.048
• InChiKey: PLFICSJYBCVEFA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  溴 、 tris(N,N-dimethyldithiocarbamato)cobalt(III) 以 氯仿 为溶剂， 生成 [3,6-di(dimethyliminio)-1,2,4,5-tetrathian]CoBr4
  参考文献：
  名称：

  Khitrich; Seifullina, Russian Journal of Coordination Chemistry, 2000, vol. 26, # 11, p. 798 - 803

  摘要：

  DOI：

文献信息

• Interaction between N,N,N′,N′-tetramethylthiuram disulfide and cobalt(II) salts: Dependence of the product composition and structure on the nature of the anion
  作者：N. V. Khitrich、I. I. Seifullina、S. E. Nefedov、A. V. Mazepa

  DOI：10.1134/s0036023606070059

  日期：2006.7

  The reaction between CoX2 (X = Br, I, NCS, NO3) and N,N,N',N'-tetramethylthiuram disulfide is found to be a redox process. Irrespective of the anion, it yields cobalt(III) dimethyldithiocarbamate Co(Me(2)Dtc)(3)}. The other products vary in number and composition: Me(4)Ditt[CoBr4] forms for X = Br; Me(2)Tmi[I-3], S, and Co(Me(2)Dtc)(3) center dot I-2, for X = I; [Co(Me(2)Ditc)(4)](NCS)(2), for X = NCS; CoSO4 center dot 7H(2)O and NO, for X = NO3 (Me(4)Ditt = 3,6-di(dimethyliminio)-1,2,4,5-tetrathian, Me(2)Tmi = dimethylthioxomethylideneimonium, and Me(2)Ditc = dimethyldithiocarbamatoisothiocyanate). The compounds have been characterized by chemical analysis, X-ray diffraction, mass spectrometry, conductivity measurements, IR and electronic spectroscopy, and magnetic measurements. The structure of Co(Me(2)Dtc)(3) center dot I-2 was determined by X-ray crystallography.