2,3-bis(2-pyridyl)quinoxaline molybdenumtetracarbonyl | 148480-65-3

• 英文名称: 2,3-bis(2-pyridyl)quinoxaline molybdenumtetracarbonyl
• CAS: 148480-65-3
• 化学式: C₂₆H₁₂Mo₂N₄O₈
• 分子量: 700.283
• InChiKey: RMLVUAMYZMVGIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2,3-bis(2-pyridyl)quinoxaline molybdenumtetracarbonyl 在 CH₃CN 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of mono- and binuclear [{Mo(CO)3L}n(dpq)] [n = 1,2; L = CO, MeCN, PPh3; dpq = 2,3-bis(2-pyridyl)quinoxaline] complexes and heterobimetallic adduct formation with hexafluoroacetylacetonatecobalt(II)

  摘要：

  The new compounds [{MO(CO)4}n(dpq)] [n = 1,2; dpq = 2,3-bis(2-pyridyl) quinoxaline] on refluxing in MeCN produce the acetonitrile complexes [{Mo(CO)3 (NCMe)}n(dpq)] (n = 1,2). These acetonitrile derivatives behave as precursors for the tricarbonyl-based fragments [{MO(CO)3}n(dpq)] (n = 1,2); they react in CH2Cl2 at room temperature with PPh3 to afford the [{Mo(CO)3(PPh3)}n(dpq)] (n = 1,2) complexes. In addition, the ligating properties of the novel mononuclear products [Mo(CO)4(dpq)] and [Mo(CO)3(PPh3)(dpq)] towards [Co(hfacac)2] are also reported. The new substances were characterized by IR and electronic spectroscopy.

  DOI：

  10.1016/s0277-5387(00)87049-7
• 作为产物：
  描述：

  2,3-二吡啶-2-基喹喔啉 、 molybdenum hexacarbonyl 以 苯 为溶剂， 以81%的产率得到2,3-bis(2-pyridyl)quinoxaline molybdenumtetracarbonyl
  参考文献：
  名称：

  Synthesis of mono- and binuclear [{Mo(CO)3L}n(dpq)] [n = 1,2; L = CO, MeCN, PPh3; dpq = 2,3-bis(2-pyridyl)quinoxaline] complexes and heterobimetallic adduct formation with hexafluoroacetylacetonatecobalt(II)

  摘要：

  The new compounds [{MO(CO)4}n(dpq)] [n = 1,2; dpq = 2,3-bis(2-pyridyl) quinoxaline] on refluxing in MeCN produce the acetonitrile complexes [{Mo(CO)3 (NCMe)}n(dpq)] (n = 1,2). These acetonitrile derivatives behave as precursors for the tricarbonyl-based fragments [{MO(CO)3}n(dpq)] (n = 1,2); they react in CH2Cl2 at room temperature with PPh3 to afford the [{Mo(CO)3(PPh3)}n(dpq)] (n = 1,2) complexes. In addition, the ligating properties of the novel mononuclear products [Mo(CO)4(dpq)] and [Mo(CO)3(PPh3)(dpq)] towards [Co(hfacac)2] are also reported. The new substances were characterized by IR and electronic spectroscopy.

  DOI：

  10.1016/s0277-5387(00)87049-7