[NBu4][Ni(C6F5)2(S(O)P(C5H4FeC5H5)(O(i)Pr))] | 691873-68-4

• 英文名称: [NBu4][Ni(C6F5)2(S(O)P(C5H4FeC5H5)(O(i)Pr))]
• CAS: 691873-68-4
• 化学式: C₁₆H₃₆N*C₂₅H₁₆F₁₀FeNiO₂PS
• 分子量: 958.43
• InChiKey: BGJUEOJAGVKSEE-XMWANKNGSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (NBu4)2{(C6F5)2Ni(μ-OH)2Ni(C6F5)2} 、 2,4-diferrocenyl-1,3-dithiadiphosphetane-2,4-disulfide 、 异丙醇 以 二氯甲烷 、 异丙醇 为溶剂， 以68%的产率得到[NBu4][Ni(C6F5)2(S(O)P(C5H4FeC5H5)(O(i)Pr))]
  参考文献：
  名称：

  Organometallic nickel(II) complexes with dithiophosphate, dithiophosphonate and monothiophosphonate ligands

  摘要：

  The hydroxo complex [NBu4](2)[Ni-2(C6F5)(4)(mu-OH)(2)] reacts with ammonium O, O'-dialkyldithiophosphates, O-alkyl-p-methoxyphenyldithiophosphonate acids and ammonium O-alkylferrocenyldithiophosphonates in dichloromethane under mild conditions to give, respectively, [NBu4][Ni(C6F5)(2){S(S)P(OR)(2)}] (R=Me (1), Et (2), Pr-i (3)) and [NBu4][Ni(C6F5)(2){S(S)P(OR)Ar}] (Ar=p-MeOC6H4, R = Me (4), Et (5), Pr-i (6); Ar = ferrocenyl; R = Me (7), Et (8), Pr-i (9)). The monothiophosphonate nickel complexes [NBu4][Ni(C6F5)(2) {S(S)P(OR)(ferrocenyl))] (R=Et (10), Pr-i (11)) are obtained by reaction of the hydroxo complex with O-alkylferrocenyldithiophosphonate acids. Analytical (C, H, N, S), conductivity, and spectroscopic (IR, H-1, F-19 and P-31 NMR, and FAB-MS) data were used for structural assignments. A single-crystal X-ray diffraction study of [NBu4][Ni(C6F5)(2){S(S)P(OMe)(p-MeOC6H4)}] (4) and [NBu4][Ni(C6F5)(2){S(O)P(OEt)(ferrocenyl)}] (10) shows that in both cases the coordination around the nickel atom es essentially square planar with NiC2S2 and NiC2SO central cores, respectively. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.06.013