[AlNa(tris(2-oxy-4,6-di-tert-butyl-benzyl)amine)Me(THF)2] | 1333519-47-3

• 英文名称: [AlNa(tris(2-oxy-4,6-di-tert-butyl-benzyl)amine)Me(THF)2]
• CAS: 1333519-47-3
• 化学式: C₅₄H₈₅AlNNaO₅
• 分子量: 878.244
• InChiKey: ARVYOZHVXMWZCF-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [AlNa(tris(2-oxy-4,6-di-tert-butyl-benzyl)amine)Me(THF)2] 、 苯甲醇 以 甲苯 为溶剂， 以71%的产率得到[AlNa(tris(2-oxy-4,6-di-tert-butyl-benzyl)amine)(benzyloxy)(THF)2]
  参考文献：
  名称：

  Multimetallic Synergic Sedation of a Labile Sodium Atrane: Synthesis and Characterization of a Tetranuclear Sodium Atrane Cation Complex

  摘要：

  A series of sodium and aluminum atrane complexes of Na3L(THF)(5) (1), [AlLMe][Na4L(THF)(6)] (2), AlL(THF) (3), AlNaLMe(THF)(2) (4), and AlNaLOBn(THF)(2) (5), wherein L = tris(2-oxy-4,6-di-tert-butyl-benzyl)amine, were synthesized and characterized by NMR, X-ray crystallography, and elemental analysis. The trinuclear sodium atrane complex of Na3L(THF)(5) (1) is labile at room temperature; however, the tetranuclear sodium atrane cation in complex 2 can be stabilized by a multimetallic synergetic effect due to a firm interaction ring of -[Na-O-benzene](3)-. Complex 2 is also the first example of a sodatrane and alumatrane ion-paired complex in which both the cationic and anionic moieties contain an atrane ligand.

  DOI：

  10.1021/ic2013123
• 作为产物：
  描述：

  四氢呋喃 、 tris(4,6-di-tert-butyl-2-hydroxybenzyl)amine 、 三甲基铝 、 sodium 以 四氢呋喃 、 正己烷 为溶剂， 以61%的产率得到[AlNa(tris(2-oxy-4,6-di-tert-butyl-benzyl)amine)Me(THF)2]
  参考文献：
  名称：

  Multimetallic Synergic Sedation of a Labile Sodium Atrane: Synthesis and Characterization of a Tetranuclear Sodium Atrane Cation Complex

  摘要：

  A series of sodium and aluminum atrane complexes of Na3L(THF)(5) (1), [AlLMe][Na4L(THF)(6)] (2), AlL(THF) (3), AlNaLMe(THF)(2) (4), and AlNaLOBn(THF)(2) (5), wherein L = tris(2-oxy-4,6-di-tert-butyl-benzyl)amine, were synthesized and characterized by NMR, X-ray crystallography, and elemental analysis. The trinuclear sodium atrane complex of Na3L(THF)(5) (1) is labile at room temperature; however, the tetranuclear sodium atrane cation in complex 2 can be stabilized by a multimetallic synergetic effect due to a firm interaction ring of -[Na-O-benzene](3)-. Complex 2 is also the first example of a sodatrane and alumatrane ion-paired complex in which both the cationic and anionic moieties contain an atrane ligand.

  DOI：

  10.1021/ic2013123