[PdClMe(3,6-di((2,6-diisopropylphenyl)iminomethyl)pyridazine)] | 1156486-86-0

• 英文名称: [PdClMe(3,6-di((2,6-diisopropylphenyl)iminomethyl)pyridazine)]
• CAS: 1156486-86-0；1156501-91-5
• 化学式: C₃₁H₄₁ClN₄Pd
• 分子量: 611.566
• InChiKey: RUKMJXJWXAMLOK-FPGONOFRSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 [PdClMe(3,6-di((2,6-diisopropylphenyl)iminomethyl)pyridazine)] 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以98%的产率得到[Pd2Me2(μ-Cl)(3,6-di((2,6-diisopropylphenyl)iminomethyl)pyridazine)]BF4
  参考文献：
  名称：

  Synthesis and Characterization of Proximal Dinuclear Complexes of Palladium Supported by 2,6-Bis(arylimino)phenoxy (aryl = 2,6-diisopropylphenyl and 2,4,6-tri-tert-butylphenyl) and 3,6-Bis(imino(2,6-diisopropylphenyl))pyridazine Ligands

  摘要：

  Two kinds of binucleating ligands, 2,6-bis(arylimino)phenoxy (1a: aryl = 2,6-diisopropylphenyl; 1b: aryl = 2,4,6-tri-tert-butylphenyl) and 3,6-bis(imino(2,6-diisopropylphenyl))pyridazine (2), were prepared, and their proximal complexation with two palladium atoms was studied. Treatment of the sodium compounds of 1a,b with 2 equiv of PdCl2(PhCN)(2) and PdMeCl(cod) afforded the corresponding homobimetallic complexes, [2,6-bis(arylimino)phenoxy][RPd(mu-Cl)PdR] (4a: R = Cl, aryl = 2,6-diisopropylphenyl; 4b: R = Cl, aryl = 2,4,6-tri-tert-butylphenyl; 7a: R = Me, aryl = 2,6-diisopropylphenyl; 7b: R = Me, aryl = 2,4,6-tri-tert-butylphenyl), whose structures were characterized spectroscopically and crystallographically. In the reaction between the sodium compound of la with I equiv of PdCl2(PhCN)(2), we detected the NaCl adduct of mononuclear palladium species 5a, which, upon release of NaCl, formed a dimeric complex, ([2,6-bis(2,6-diisopropylphenylimino)phenoxy](PdCl])(2) (4a), as confirmed by X-ray analysis. Complexation of 2 with 2 equiv of PdCl2(PhCN)(2) and PdMeCl(cod) in the presence of I equiv of AgBF4 resulted in the formation of the corresponding cationic complexes ([3,6-bis(imino(2,6-diisopropylphenyl))pyridazine][RPd(mu-Cl)PdR])(BF4) (9a: R = Cl; 9b: R = Me), whose RPd(mu-Cl)PdR skeletons (R = Cl and Me) were revealed spectroscopically and crystallographically.

  DOI：

  10.1021/om900043u
• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 3,6-二((2,6-二异丙基苯基)亚氨基甲基)哒嗪 以 二氯甲烷 为溶剂， 以99%的产率得到[PdClMe(3,6-di((2,6-diisopropylphenyl)iminomethyl)pyridazine)]
  参考文献：
  名称：

  Synthesis and Characterization of Proximal Dinuclear Complexes of Palladium Supported by 2,6-Bis(arylimino)phenoxy (aryl = 2,6-diisopropylphenyl and 2,4,6-tri-tert-butylphenyl) and 3,6-Bis(imino(2,6-diisopropylphenyl))pyridazine Ligands

  摘要：

  Two kinds of binucleating ligands, 2,6-bis(arylimino)phenoxy (1a: aryl = 2,6-diisopropylphenyl; 1b: aryl = 2,4,6-tri-tert-butylphenyl) and 3,6-bis(imino(2,6-diisopropylphenyl))pyridazine (2), were prepared, and their proximal complexation with two palladium atoms was studied. Treatment of the sodium compounds of 1a,b with 2 equiv of PdCl2(PhCN)(2) and PdMeCl(cod) afforded the corresponding homobimetallic complexes, [2,6-bis(arylimino)phenoxy][RPd(mu-Cl)PdR] (4a: R = Cl, aryl = 2,6-diisopropylphenyl; 4b: R = Cl, aryl = 2,4,6-tri-tert-butylphenyl; 7a: R = Me, aryl = 2,6-diisopropylphenyl; 7b: R = Me, aryl = 2,4,6-tri-tert-butylphenyl), whose structures were characterized spectroscopically and crystallographically. In the reaction between the sodium compound of la with I equiv of PdCl2(PhCN)(2), we detected the NaCl adduct of mononuclear palladium species 5a, which, upon release of NaCl, formed a dimeric complex, ([2,6-bis(2,6-diisopropylphenylimino)phenoxy](PdCl])(2) (4a), as confirmed by X-ray analysis. Complexation of 2 with 2 equiv of PdCl2(PhCN)(2) and PdMeCl(cod) in the presence of I equiv of AgBF4 resulted in the formation of the corresponding cationic complexes ([3,6-bis(imino(2,6-diisopropylphenyl))pyridazine][RPd(mu-Cl)PdR])(BF4) (9a: R = Cl; 9b: R = Me), whose RPd(mu-Cl)PdR skeletons (R = Cl and Me) were revealed spectroscopically and crystallographically.

  DOI：

  10.1021/om900043u