| 626243-07-0

• CAS: 626243-07-0
• 化学式: C₄H₁₂N*C₃₂H₃₆AlS₄
• 分子量: 650.029
• InChiKey: RVRWRBCHPGOTBA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-二甲基巯基苯酚 、 alane N,N-dimethylethylamine complex 以 乙醚 为溶剂， 以27%的产率得到
  参考文献：
  名称：

  Synthetic and structural studies on aluminium thiolate complexes

  摘要：

  The reaction between [AlH3(NMe2Et)] and 1 equiv. of t-BuSH resulted in the isolation of colourless crystals of [Al(S-t-Bu)(3)(NMe2Et)]. The reaction of [AlH3(NMe2Et)] and 1 equiv. of 2,6-Me2C6H3SH afforded colourless crystals of [HNMe2Et][Al(SC6H3Me2-2,6)(4)]. The related reaction of [AlH3(OEt2)] (generated in situ from AlCl3 and 3 equiv. of LiAlH4) and 2,6-Me2C6H3SH in diethyl ether resulted in the formation of [Al(SC6H3Me2-2,6)(3)(OEt2)]. However, the ionic compound [Li(OEt2)(3)][Al(SC6H3Me2-2,6)(4)] can be isolated from the reaction between [AlH3(OEt2)] and 2,6-Me2C6H3SH, when incomplete reaction of AlCl3 with LiAlH4 occurs before the addition of the thiol. The X-ray crystal structures of all the compounds have been determined. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00351-6