| 166603-78-7

• CAS: 166603-78-7
• 化学式: C₁₇H₁₈Cl₂MnN₄O₂
• 分子量: 436.2
• InChiKey: NVEGVQNIGSXXQV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 1,3-bis(1H-benzimidazol-2-yl)-2-oxapropane 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Novel Reactivity of the Dioxygen Molecule in the Presence of a Manganese(II) Complex and Reducing Agents

  摘要：

  A manganese(II) complex with pentadentate ligand derived from 2,6-diacetylpyridine and triethylenetetramine exhibits high activity for activation of dioxygen in the presence of several aliphatic aldehydes, but the activities of other manganese(II) compounds with tripod-like ligands such as tris(2-benzimidazolylmethyl)amine or bis(2-benzimidazolylmethyl) ether are almost negligible. On the basis of these facts including electrochemical data under dioxygen atmosphere, the importance of an intermediate complex formation among aliphatic aldehyde, Mn(II) complex, and dioxygen is pointed out; in the intermediate, the dioxygen molecule is assumed to coordinate to a manganese(II) ion by hydrogen bonding with the hydrogen atom of the chelate (-NH group), and the novel reactivity of dioxygen, i.e., the dioxygen molecule accepts an electron from the aldehyde through formation of the intermediate to yield an organic peracid without the change of the oxidation state of the metal ion, is postulated.

  DOI：

  10.1021/ic00118a008