| 1085234-49-6

• CAS: 1085234-49-6
• 化学式: C₂₆H₃₈Ti
• 分子量: 398.468
• InChiKey: JGKSWDGDRISOAV-AEOSXFHFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 2-氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 6.0h， 以257 mg的产率得到3a,6,7,7a-tetrapropyl-3a,7a-dihydro-1H-indene
  参考文献：
  名称：

  Separation of Five Linearly Aligned Carbons into Two-Carbon and Three-Carbon Groups on Titanium

  摘要：

  Five carbons linearly aligned in a dihydroindene titanium complex were separated into a two-carbon group and a three-carbon group on titanium when the complex was treated with 2-aminopyridine. The protonolysis product, dihydroindene with two alkyl groups at both bridge-head positions, was obtained in high yield.

  DOI：

  10.1021/acs.organomet.6b00112
• 作为产物：
  描述：

  bis(cyclopentadienyl)-2,3,4,5-tetrapropyl-1-titanacyclopentadiene 生成
  参考文献：
  名称：

  Separation of Five Linearly Aligned Carbons into Two-Carbon and Three-Carbon Groups on Titanium

  摘要：

  Five carbons linearly aligned in a dihydroindene titanium complex were separated into a two-carbon group and a three-carbon group on titanium when the complex was treated with 2-aminopyridine. The protonolysis product, dihydroindene with two alkyl groups at both bridge-head positions, was obtained in high yield.

  DOI：

  10.1021/acs.organomet.6b00112

文献信息

• Once Cleaved C−C Bond Was Reformed: Reversible C−C Bond Cleavage of Dihydroindenyltitanium Complexes
  作者：Tamotsu Takahashi、Zhiyi Song、Yi-Fang Hsieh、Kiyohiko Nakajima、Ken-ichiro Kanno

  DOI：10.1021/ja805352z

  日期：2008.11.19

  The once cleaved carbon-carbon bond of the Cp moiety in 2 was recombined in indene products. Aslo, we propose a novel mechanism for the cleavage of the carbon-carbon bond of the Cp moiety.

  2 中 Cp 部分的一次断裂碳-碳键在茚产品中重新结合。同样，我们提出了一种新的裂解 Cp 部分的碳-碳键的机制。