[(η(5)-C5H5)Ru(η(2)-PPh2N(Ph)PPh2)(CO)]Cl | 212056-58-1

• 英文名称: [(η(5)-C5H5)Ru(η(2)-PPh2N(Ph)PPh2)(CO)]Cl
• CAS: 212056-58-1
• 化学式: C₃₆H₃₀NOP₂Ru*Cl
• 分子量: 691.111
• InChiKey: LCBACRRVAYEVMI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(三苯基膦)环戊二烯基氯化钌(II) 、 一氧化碳 、 bis(diphenylphosphanyl)(phenyl)amine 以 甲苯 为溶剂， 以75%的产率得到[(η(5)-C5H5)Ru(η(2)-PPh2N(Ph)PPh2)(CO)]Cl
  参考文献：
  名称：

  Transition metal chemistry of phosphorus based ligands. Ruthenium(II) chemistry of bis(phosphino)amines, X2PN(R)PX2 (R=H or Ph, X=Ph; R=Ph, X2=O2C6H4)

  摘要：

  Reactions of CpRuCl(PPh3)(2) with bis(phosphino)amines, X2PN(R)PX2 (1 R = H, X = Ph; 2 R = X = Ph; 3 R = Ph, X-2 = O2C6H4) give neutral or cationic mononuclear complexes depending on the reaction conditions. Reaction of 1 with CpRuCl(PPh3)(2) gives one neutral complex, [CpRu(Cl)(eta(2)-Ph2PN(H)PPh2)] (4) and two cationic complexes, [CpRu(eta(2)-Ph2PN(H)PPh2)(eta(1)-Ph2PN(H)PPh2)]Cl (5) and [CpRu(PPh3)(eta(2)-Ph2PN(H)PPh2)]Cl (6), whereas the reaction of 2 with CpRuCl(PPh3)(2) leads only to the isolation of cationic complex, [CpRu(PPh3)(eta(2)-Ph2PN(Ph)PPh2)]Cl (7). The catechol derivative 3, in a similar reaction, affords an interesting mononuclear complex [CpRu(PPh3){eta(1)-(C4H4O2)PN(Ph)P(O2H4C6)}(2)]Cl (8) containing two monodentate bis(phosphino)amine ligands. The structural elucidation of the complexes was carried out by elemental analyses, IR and NMR spectroscopic data. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00464-1