[(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(μ-S)2Ru(η6-benzene)] | 912672-31-2

• 英文名称: [(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(μ-S)2Ru(η6-benzene)]
• CAS: 912672-31-2
• 化学式: C₄₀H₄₄GeRuS₂
• 分子量: 762.581
• InChiKey: MWQZNNKSTPVMJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(μ-S)2Ru(η6-benzene)] 、 三苯基膦 以 甲苯 为溶剂， 以82%的产率得到[(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(μ-S)2Ru(PPh3)]
  参考文献：
  名称：

  Synthesis of Oxo- and Sulfido-Bridged Germanium−Ruthenium Complexes and Reactions on the Chalcogenido Bridges

  摘要：

  A series of heterodinuclear germanium-ruthenium complexes having sulfido/oxo bridges, Dmp(Dep)Ge(mu-E-1)(mu-E-2)Ru(eta(6)-arene) (E-1, E-2 = S, O; arene) benzene, p-cymene; Dmp = 2,6-dimesitylphenyl, Dep) 2,6-diethylphenyl) were synthesized by the reaction of [Ru(eta(6)-arene)Cl-2](2) and the corresponding diarylgermanedichalcogenoles, Dmp(Dep)Ge((EH)-H-1)((EH)-H-2). The reaction with tertiary phosphines gave the corresponding adducts Dmp(Dep)Ge(mu-S)(mu-E)Ru(PR3) (E = S, O; R = Ph, Et), in which the arene ligand on the ruthenium was replaced by a mesityl group of Dmp. When Dmp(Dep)Ge(mu-S)(2)Ru(PPh3) was treated with the Bronsted acids H(OEt2)(2)BAr4F and HOTf, a sulfido bridge was protonated to afford [Dmp(Dep)Ge(mu-S)(mu-SH)Ru(PPh3)]X (X = BAr4F, OTf). Likewise, the methylation reaction with Me3OBF4 proceeded at a mu-S, generating [Dmp(Dep)Ge(mu-S)(mu-SMe)Ru(PPh3)](BF4). On the other hand, protonation of Dmp(Dep)Ge(mu-S)(mu-O)Ru(PPh3) gave a mu-OH complex, [Dmp(Dep)Ge(mu-S)(mu-OH)Ru(PPh3)](+), while the analogous methylation afforded the cationic mu-SMe complex [Dmp(Dep)Ge(mu-SMe)(mu-O)Ru(PPh3)](+).

  DOI：

  10.1021/om060449m
• 作为产物：
  描述：

  [RuCl2(benzene)]2 、 (2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(SH)2 在 BuLi 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以84%的产率得到[(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(μ-S)2Ru(η6-benzene)]
  参考文献：
  名称：

  Synthesis of Oxo- and Sulfido-Bridged Germanium−Ruthenium Complexes and Reactions on the Chalcogenido Bridges

  摘要：

  A series of heterodinuclear germanium-ruthenium complexes having sulfido/oxo bridges, Dmp(Dep)Ge(mu-E-1)(mu-E-2)Ru(eta(6)-arene) (E-1, E-2 = S, O; arene) benzene, p-cymene; Dmp = 2,6-dimesitylphenyl, Dep) 2,6-diethylphenyl) were synthesized by the reaction of [Ru(eta(6)-arene)Cl-2](2) and the corresponding diarylgermanedichalcogenoles, Dmp(Dep)Ge((EH)-H-1)((EH)-H-2). The reaction with tertiary phosphines gave the corresponding adducts Dmp(Dep)Ge(mu-S)(mu-E)Ru(PR3) (E = S, O; R = Ph, Et), in which the arene ligand on the ruthenium was replaced by a mesityl group of Dmp. When Dmp(Dep)Ge(mu-S)(2)Ru(PPh3) was treated with the Bronsted acids H(OEt2)(2)BAr4F and HOTf, a sulfido bridge was protonated to afford [Dmp(Dep)Ge(mu-S)(mu-SH)Ru(PPh3)]X (X = BAr4F, OTf). Likewise, the methylation reaction with Me3OBF4 proceeded at a mu-S, generating [Dmp(Dep)Ge(mu-S)(mu-SMe)Ru(PPh3)](BF4). On the other hand, protonation of Dmp(Dep)Ge(mu-S)(mu-O)Ru(PPh3) gave a mu-OH complex, [Dmp(Dep)Ge(mu-S)(mu-OH)Ru(PPh3)](+), while the analogous methylation afforded the cationic mu-SMe complex [Dmp(Dep)Ge(mu-SMe)(mu-O)Ru(PPh3)](+).

  DOI：

  10.1021/om060449m