di-μ-chlorodichlorobis(η(2)-cyclodecene)dipalladium(II) | 209471-93-2

• 英文名称: di-μ-chlorodichlorobis(η(2)-cyclodecene)dipalladium(II)
• CAS: 209471-93-2
• 化学式: C₂₀H₃₆Cl₄Pd₂
• 分子量: 631.158
• InChiKey: QJNVBABYCXNQLP-BJTMLYKVSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (Z)-cyclodecene 、 palladium dichloride 在 NaCl 、 NaOAc 作用下， 以 溶剂黄146 为溶剂， 以86%的产率得到di-μ-chlorodichlorobis(η(2)-cyclodecene)dipalladium(II)
  参考文献：
  名称：

  η³-Allylpalladium Complexes from Medium-Ring Cycloalkenes

  摘要：

  The dimeric eta(3)-allylpalladium chloride complexes formed from various cycloalkenes (C-7-C-13) and some methyl-and tert-butyl-substituted cycle alkenes have be en characterized by H-1 and C-13 NMR spectroscopy and in selected cases by X-ray crystallography. The formation of syn and anti isomers in the larger ring systems is demonstrated, and complexes with a rearranged ring system are formed from tert-butylcyclodecene and tert-butylcyclododecene. The sesquiterpene, carophyllene, is shown to form an eta(3)-allyl exocyclic complex, exclusively from the (E)-double bond. Cis and trans isomers, with respect to allyl group orientation in these halo-bridged dimers, have been identified by low-temperature (190K) NMR spectroscopy, and their interconversion (Delta G(double dagger) approximate to 11 kcal/mol) is considered to involve a "cubic" eta(3)-allylpalladium chloride tetramer.

  DOI：

  10.1021/om971132c