(1,4-bis(2,6-diisopropylphenyl)-1,4-diazabutadiene)(tetrafluorethene)nickel(0) | 134572-97-7

• 英文名称: (1,4-bis(2,6-diisopropylphenyl)-1,4-diazabutadiene)(tetrafluorethene)nickel(0)
• CAS: 134572-97-7
• 化学式: C₂₈H₃₆F₄N₂Ni
• 分子量: 535.291
• InChiKey: XURDKTXQFYJECL-HQRQQUDRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (1,4-bis(2,6-diisopropylphenyl)-1,4-diazabutadiene)(tetrafluorethene)nickel(0) 、 乙烯 以 乙醚 为溶剂， 以40%的产率得到(1,4-bis(2,6-diisopropylphenyl)-1,4-diazabutadiene)nickela-2,2,3,3-tetrafluorcyclopentane
  参考文献：
  名称：

  Synthese und Reactivität von (2,6-iPr2Ph-dad)Ni(C2F4)

  摘要：

  Upon warming the reaction mixture of Ni(cdt), C2F4, and 2,6-(i)Pr2Ph-dad in THF from - 78-degrees-C to room temperature the red-violet complex (2,6-(i)Pr2Ph-dad)Ni(C2F4) (1) is obtained. 1 reacts with ethene already at - 78-degrees-C by coupling of the olefinic ligands with the nickel atom to form the blue nickelatetrafluoro-cyclopentane compound (2,6-(i)Pr2Ph-dad)Ni(C2H4C2F4) (2).

  DOI：

  10.1016/0022-328x(91)86393-5
• 作为产物：
  描述：

  [Ni(1,5,9-cyclododecatriene)] 、 N,N'-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene 、 四氟乙烯 以 乙醚 为溶剂， 以85%的产率得到(1,4-bis(2,6-diisopropylphenyl)-1,4-diazabutadiene)(tetrafluorethene)nickel(0)
  参考文献：
  名称：

  Synthese und Reactivität von (2,6-iPr2Ph-dad)Ni(C2F4)

  摘要：

  Upon warming the reaction mixture of Ni(cdt), C2F4, and 2,6-(i)Pr2Ph-dad in THF from - 78-degrees-C to room temperature the red-violet complex (2,6-(i)Pr2Ph-dad)Ni(C2F4) (1) is obtained. 1 reacts with ethene already at - 78-degrees-C by coupling of the olefinic ligands with the nickel atom to form the blue nickelatetrafluoro-cyclopentane compound (2,6-(i)Pr2Ph-dad)Ni(C2H4C2F4) (2).

  DOI：

  10.1016/0022-328x(91)86393-5