| 239475-82-2

• CAS: 239475-82-2
• 化学式: C₂₈H₁₉NO₄PRe
• 分子量: 650.644
• InChiKey: RQVIKDMUJVLLKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η1-PhCH2)Re(CO)5 、 四苯基氨化膦 以 petroleum ether 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Orthomanganation of the iminophosphorane Ph3PNPh, and of triphenylarsine-oxide and -sulfide

  摘要：

  Two novel types of cyclometallated rings are described. Orthomanganation of Ph3P=NPh gave Ph2P[=NPh]C6H4Mn(CO)(4), 5a, containing an N,C-chelated five-membered ring, characterised by single crystal X-ray determinations of two distinct polymorphs. Solutions of 5a are thermochroic. The rhenium analogue of 5a was also prepared. Reaction of Ph3As=X (X=O, S) with PhCH2Mn(CO)(5) gave the first examples of orthometallated triphenylarsine chalcogenides. The example with X=O was characterised structurally. Attempted cyclomanganation of Ph3As was unsuccessful, but gave (in low yield) a dimanganese complex containing mu-AsPh2 and mu-eta(1), eta(6)-benzyl ligands. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00007-8