bis[μ-(adamant-1-yl)carboxylato]bis[(η2:η2-norborna-2,5-diene)rhodium] | 756886-83-6

• 英文名称: bis[μ-(adamant-1-yl)carboxylato]bis[(η2:η2-norborna-2,5-diene)rhodium]
• CAS: 756886-83-6
• 化学式: C₃₆H₄₆O₄Rh₂
• 分子量: 748.57
• InChiKey: QCPATANDVKZFAV-SUQHLKOJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  di-μ-chlorobis(norbornadiene)dirhodium(I) 、 silver adamantane-1-carboxylate 以 水 为溶剂， 以68%的产率得到bis[μ-(adamant-1-yl)carboxylato]bis[(η2:η2-norborna-2,5-diene)rhodium]
  参考文献：
  名称：

  Hydroformylation of alkenes catalyzed by new dinuclear aryloxide- and carboxylate-bridged rhodium complexes

  摘要：

  The new dinuclear aryloxide- and carboxylate-bridged rhodium complexes bis[mu-(2-methylphenolato)]bis[(eta(2):eta(2)-cycloocta-1,5-diene)rhodium], di(mu-docosanoato)bis[(eta(2):eta(2)-norborna-2,5-diene)rhodium] and bis[(mu-(adamant-1-yl)carboxylato]bis[(eta(2):eta(2)-norborna-2,5-diene)rhodium] have been prepared. The complexes were tested as catalysts in the hydroformylation of styrene with a total pressure of CO/H-2 (1:1) of 1000 psi, at 25 and 60 degreesC, and displayed a regio selectivity towards the branched aldehyde of up to 97%. The same complexes as catalysts in the hydroformylation of 1-octene displayed a regio selectivity for the linear aldehyde of up to 55%. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.05.014