[Fe(C5H4C3N2HMe4OH)(C5H4C3N2HMe4O)][Co(hexafluoroacetylacetonato)3] | 640720-71-4

• 英文名称: [Fe(C5H4C3N2HMe4OH)(C5H4C3N2HMe4O)][Co(hexafluoroacetylacetonato)3]
• CAS: 640720-71-4
• 化学式: C₁₅H₃CoF₁₈O₆*C₂₄H₃₄FeN₄O₂*H
• 分子量: 1147.56
• InChiKey: SZELOBLNUPFDGQ-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cobalt bis(1,1,1,5,5,5-hexafluoroacetylacetonato) dihydrate 、 2,2'-di(1,1'-ferrocenediyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-yl oxyl 以 正庚烷 为溶剂， 生成 [Fe(C5H4C3N2HMe4OH)(C5H4C3N2HMe4O)][Co(hexafluoroacetylacetonato)3]
  参考文献：
  名称：

  Synthesis, X-ray structure and characterization of a novel [fc(IMH)2H]+[Co(hfac)3]− salt with hydrogen bonded ferrocenyl bis(imino hydroxylamino) building blocks

  摘要：

  The reaction of ferrocenylene bis(alpha-nitronyl nitroxide) diradical (1; [fc(NIT)(2)]) with Co(hfac)(2) produces the reduction of the radical character of 1 with the formation of the diamagnetic ferroceryl bis(alpha-imino nitroxide) cation, [fc(IMH)(2)H](+), which forms with the [Co(II)hfac(3)](-), as the counterion, the complex salt 4. This salt crystallizes in the P (1) over bar spatial group exhibiting an exotic supramolecular architecture in which the molecular ions are bonded through hydrogen bonds forming single chains with a zipper-like arrangement. Remarkable is the presence in complex salt 4 of two proton tautomeric forms in the [fc(IMH)(2)H](+) units. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00502-3