Cr2Cl2(H2O)2(1-(salicylaldeneamino)-3-hydroxypropane(1-))2 | 1217495-29-8

• 英文名称: Cr2Cl2(H2O)2(1-(salicylaldeneamino)-3-hydroxypropane(1-))2
• CAS: 1217495-29-8
• 化学式: C₂₀H₂₆Cl₂Cr₂N₂O₆
• 分子量: 565.334
• InChiKey: ANMNMCKQLHEGOD-ATBHOVGYSA-J

反应信息

• 作为产物：
  描述：

  水杨醛 、 3-氨基-1-丙醇 、 chromium chloride hexahydrate 在 N(CH₂CH₃)3 作用下， 以 乙腈 为溶剂， 生成 Cr2Cl2(H2O)2(1-(salicylaldeneamino)-3-hydroxypropane(1-))2
  参考文献：
  名称：

  Spectral and physico-chemical investigations of novel homo-dinuclear di-μ2-alkoxo bridged Schiff base complexes: 57Fe Mössbauer parameters of the Fe(III) complex

  摘要：

  Spectral and molecular model computations on homo-dinuclear complexes [M2L2(H2O)(2)Cl-2] [L = 1-(salicylaldeneamino)-3-hydroxypropane, M = Cr3+, Mn3+, Fe3+, Co3+, Ni3+ or Cu3+] are consistent with a distorted hexa-coordinate geometry. X-band EPR spectral data indicated a rhombic distortion around Cu(II) ion. Magnetic moment and Fe-57 Mossbauer data confirmed a high-spin state electronic configuration (t(2g) (3)e(g)(2), S = 5/2) and asymmetric ligand environment around Fe(III) with nuclear transitions Fe(+/-3/2 -> 1/2) exhibiting Kramer's double degeneracy. The neighboring Fe(III) nuclei in the homo-dinuclear species are antiferrornagnetically coupled. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2009.12.010