(C5Me5)WRu5(μ4-C)(μ3-CCH2Ph)(μ-H)4(CO)12 | 192456-76-1

• 英文名称: (C5Me5)WRu5(μ4-C)(μ3-CCH2Ph)(μ-H)4(CO)12
• CAS: 192456-76-1
• 化学式: C₃₁H₂₆O₁₂Ru₅W
• 分子量: 1279.74
• InChiKey: WPUXLIRCIKBSMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (C5Me5)WRu5(μ5-C)(CCPh)(CO)13 、 氢气 以 甲苯 为溶剂， 以45%的产率得到(C5Me5)WRu5(μ6-C)(μ-CCH2Ph)(μ-H)2(CO)13
  参考文献：
  名称：

  Stepwise Formation of Heterometallic Cluster Compounds (C₅Me₅)WRu₅(μ₆-C)(μ-CCH₂Ph)(μ-H)₂(CO)₁₃ and (C₅Me₅)WRu₅(μ₄-C)(μ₃-CCH₂Ph)(μ-H)₄(CO)₁₂ from Ru₅(μ₅-C)(CO)₁₅. Reactivity Studies of Carbido Clusters Bearing Acetylide Ligands

  摘要：

  Treatment of the carbido cluster Ru-5(mu(5)-C)(CO)(15) with Me3NO followed by addition of the tungsten acetylide complexes LW(CO)(3)(CCPh)(L = Cp, C5Me5) affords the two heterometallic cluster complexes LWRu5(mu(5)-C)(CCPh)(CO)(15) (1a, L = Cp; 1b, L = C5Me5) and LWRu5(mu(5)-C)(CCPh)(CO)(13) (2a, L = Cp; 2b, L = C5Me5). Thermolysis of 1 results in the irreversible formation of 2. The reactivity of 2 was studied. Thus, hydrogenation of 2b furnishes the two cluster compounds (C5Me5)WRu5(mu(6)-C)(mu-CCH2Ph)(mu-H)(2)(CO) (3) and (C5Me5)WRu5(mu(4)-C)(mu(3)-CCH2Ph)(mu-H)(4)(CO)(12) (4), generated via 1,1-addition of H-2 to the ligated acetylide and concurrent formation of two or four bridging hydrides. Treatment of 3 with CO gives the octahedral cluster (C5Me5)WRu5(mu(6)-C)(mu-CCH2Ph)(CO)(14) (5). The spectral and structural properties of all species are presented and discussed.

  DOI：

  10.1021/om970211l