[Et3NH][PdCl(Me)(κ2-3-(di(2-methoxyphenyl)phosphanyl)propionate)] | 1332313-81-1

• 英文名称: [Et3NH][PdCl(Me)(κ2-3-(di(2-methoxyphenyl)phosphanyl)propionate)]
• CAS: 1332313-81-1
• 化学式: C₆H₁₆N*C₁₈H₂₁ClO₄PPd
• 分子量: 576.409
• InChiKey: XRRKATCSXOWBND-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 3-(di(2-methoxyphenyl)phosphanyl)propionic acid 、 三乙胺 以 二氯甲烷 为溶剂， 以51%的产率得到[Et3NH][PdCl(Me)(κ2-3-(di(2-methoxyphenyl)phosphanyl)propionate)]
  参考文献：
  名称：

  First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II)

  摘要：

  The P-O ligand 3-(di(2-methoxyphenyl)phosphanyl) propionic acid (HL) was synthesized by a microwave-assisted reaction of a secondary phosphane. The coordination of HL to Pt-II yielded the neutral mononuclear complex trans-[PtCl(kappa(2)-P,O-L)(kappa-P-HL)] (1), while the reaction of PdClMe(eta(4)-COD) (COD = 1,4-cyclooctadiene) with HL in the presence of NEt3 gave the anionic Pd-II compound of the formula (HNEt3)[PdClMe(kappa(2)-P,O-L)] (2). Upon crystallization of the latter compound the neutral chloridebridged dimetallic compound cis-[Pd(mu-Cl)Me(HL)](2) (3) was obtained. HL, 1 and 3 center dot CH2Cl2 have been characterized by single crystal X-ray structure analyses. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.05.020