[chloro(1-methyl-2-(naphth-9-yl-α-azo)-imidazole)mercury(II)] | 588699-09-6

• 英文名称: [chloro(1-methyl-2-(naphth-9-yl-α-azo)-imidazole)mercury(II)]
• CAS: 588699-09-6
• 化学式: C₁₄H₁₁ClHgN₄
• 分子量: 471.311
• InChiKey: JTFIDYHPOYTAGN-WXIBIURSSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  mercury(II) diacetate 、 lithium chloride 、 1-methyl-2-(naphthyl-α-azo)-imidazole 以 甲醇 为溶剂， 以41%的产率得到[chloro(1-methyl-2-(naphth-9-yl-α-azo)-imidazole)mercury(II)]
  参考文献：
  名称：

  Naphthylazoimidazole and mercury(II) complexes. Single crystal X-ray structure of 1-ethyl-2-(naphthyl-α-azo)imidazolium hexaflurophosphate

  摘要：

  1-Alkyl-2-(naphthyl-(alpha/beta)-azo)imidazole [alpha-NaiR (2)/beta-NaiR (3); R =Me (a), Et (b), CH2Ph (c)] are N,N'-bidentate chelating ligands. The structure of 1-ethyl-2-(naphthyl-alpha-azo)imidazolium hexaflurophosphate has been confirmed by single crystal X-ray structure study and shows supramolecular geometry through non-covalent interactions (C-(HF)-F-..., C-H(...)pi, pi(...)pi TC). Mercury(II) complexes of the formula Hg(NaiR)Cl-2 (4/5) have been synthesised and characterised by spectral (IR, UV-Vis and H-1 and C-13 NMR) studies. alpha-NaiR has been used to synthesise organomercury derivatives, Hg(alpha-NaiR-H)Cl (6) and the site of mercuration has been supported by charge density calculation using a semi-empirical PM3 technique. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00131-1