[(Ru(CO)2(η-C5H4Me))2(μ-C.tplbond.C)] | 213914-30-8

• 英文名称: [(Ru(CO)2(η-C5H4Me))2(μ-C.tplbond.C)]
• 英文别名: [(Ru(CO)2(η-C5H4(CH3))(μ2-CC)(Ru(CO)2(η-C5H4(CH3))]；((η-C5H4CH3)Ru(CO)2)2(μCC)；[[(η5-C5H4Me)Ru(CO)2]2(μ-CC)]；(Ru(CO)2(η5-C5H4CH3))2(μ-C.tplbond.C)；[(Ru(CO)2(η-C5H4Me))2(μ2-C.ident.C)]
• CAS: 213914-30-8
• 化学式: C₁₈H₁₄O₄Ru₂
• 分子量: 496.447
• InChiKey: MKQUAWXERVMQPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tetrakis(actonitrile)copper(I) hexafluorophosphate 、 [(Ru(CO)2(η-C5H4Me))2(μ-C.tplbond.C)] 以 四氢呋喃 为溶剂， 反应 10.0h， 以74%的产率得到
  参考文献：
  名称：

  钌乙炔基1,2-二乙烯基化合物的铜（I）和银（I）加合物的阴离子定向固态结构

  摘要：

  许多第11组盐，[MX]（M = Ag，X – = – O 3 SCF 3，– O 2 CCF 3，BF 4 –； M = Cu； X = Cl，Br）和[Cu（MeCN）4 ] [PF 6 ]中，发现与乙炔-1,2-二基的化合物不同的化学计量进行反应，[{的Ru（CO）2（η-C 5 H ^ 4 R）} 2（μ 2 -C≡C） ]（R = H，Me），得到许多复杂的阳离子。的三阳离子盐将[Ag 3（{的Ru（CO）2（η-C 5 H ^ 4 Me）的} 2（μ 2 -η 1：η 1 -C≡C））3 ]（O 3 SCF 3）3，将[Ag 3（{的Ru（CO）2（η-C 5 H ^ 4 R）} 2（μ 2 - η 1：η 1 -C≡C））（{的Ru（CO）2（η-C 5 H ^ 4 R）} 2（μ 2 -η 1：η 2 -C≡C））2 ]（BF 4）3和[Cu 3（{Ru（CO）2（η-C5

  DOI：

  10.1021/om501270u

文献信息

• Reactions of metalloalkynes
  作者：Lindsay T. Byrne、James P. Hos、George A. Koutsantonis、Brian W. Skelton、Allan H. White

  DOI：10.1016/s0022-328x(99)00666-x

  日期：2000.3

  The reactions between [Ru(CO)4(η2-C2H4)], generated in situ, and ruthenium ethyne-1,2-diyl complexes, [Ru(CO)2(η-C5H4R)}2(μ-CC)] (R=H, Me) have provided the new air-sensitive complexes [Ru4(μ4-CC)(η-C5H4R)2(μ-CO)2(CO)8] (R=H, Me) with a permetallated ethene structure, in good yield. The complexes were characterized spectroscopically and by single-crystal X-ray diffraction studies. They have an almost

  的[Ru（CO）之间的反应4（η 2 -C 2 H ^ 4）]，在原位产生的，和钌乙炔-1,2-二基配合物，[的Ru（CO）2（η-C 5 H ^ 4 - [R ）} 2（μ-CC）]（R = H，Me）的所提供的新的空气敏感的复合物的[Ru 4（μ 4 -CC）（η-C 5 H ^ 4 R）2（μ-CO）2（CO）8 ]（R = H，Me）具有全金属化的乙烯结构，收率良好。配合物通过光谱学和单晶X射线衍射研究表征。它们具有几乎平坦的开放几何形状，使C 22-易于反应的配体。在标记实验的帮助下，明确确定了配合物在13 C 1 H} -NMR光谱中归因于C 2 2-的共振。
• Reactions of metalloalkynes. New C2 bonding mode in a trimetallic complexElectronic supplementary information (ESI) available: Synthesis and characterisation of complexes 4a and 4b. See http://www.rsc.org/suppdata/cc/b1/b110930h/This paper constitutes Part 4 of the series.
  作者：Christopher S. Griffith、George A. Koutsantonis、Brian W. Skelton、Allan H. White

  DOI：10.1039/b110930h

  日期：2002.9.11

  The reaction of the silver complexes [((Ru(CO)2(eta-C5H4R))2(mu-C identical to C))3Ag3][BF4]3 (R = H or Me) with [RuCl(CO)2(eta-C5H4R)] at room temperature gave the new trimetallic complexes [(Ru(CO)2(eta-C5H4R))3(eta 1:eta 2-C identical to C))][BF4] which contain the C2(2-) ligand surrounded by ruthenium atoms; these complexes do not contain metal-metal bonds and were characterised by single crystal

  银络合物[（（（Ru（CO）2（eta-C5H4R））2（μ-C与C相同））3Ag3] [BF4] 3（R = H或Me）与[RuCl（CO）2 （eta-C5H4R）]在室温下得到新的三金属配合物[（Ru（CO）2（eta-C5H4R））3（eta 1：eta 2-C与C相同））] [BF4]其中含有C2（ 2-）被钌原子包围的配体；这些配合物不包含金属-金属键，并且通过单晶X射线研究表征。固态结构没有保留在溶液中，在NMR时间尺度上发现它是通量的，并且假定的动态过程可以描述为“轴承状”。
• Reactions of metalloalkynes 3. Facile synthesis of pentanuclear ruthenium clusters. X-ray structures of [Ru5(μ5-CC)(η-C5H4R)2(dppm)(μ2-CO)2(CO)7] (R=H, CH3)
  作者：Lindsay T Byrne、Christopher S Griffith、James P Hos、George A Koutsantonis、Brian W Skelton、Allan H White

  DOI：10.1016/s0022-328x(98)00525-7

  日期：1998.8

  The reaction of the activated cluster compound, Ru3(CO)10(dppm), 1, with two ethyne-1,2-diyl compounds, [Ru(CO)2(η-C5H4R)}2(μ-CC)], (2a, R=H; 2b, R=CH3) has resulted in a facile and high yielding synthesis of medium nuclearity cluster compounds, [Ru5(μ5-CC)(η-C5H4R)2(dppm)(μ2-CO)2(CO)7], (3a, R=H; 3b, R=CH3). The core of these compounds incorporate an open and accessible carbide ligand bound to

  活化的簇状化合物Ru 3（CO）10（DPPM）1与两种乙炔1,2-二基化合物[Ru（CO）2（η- C 5 H 4 R）} 2（μ -CC）]，（图2a，R = H;图2b，R = CH 3），导致以容易的和介质核性簇化合物，[Ru中的高产合成5（μ 5 -CC）（η -C 5 ħ 4 R）2（DPPM）（μ 2 -CO）2（CO）图7 ]，（3a，R ＝ H；3b，R ＝ CH 3）。这些化合物的核心结合了一个开放且易接近的碳化物配体，该配体与一个相对罕见的尖峰蝴蝶金属骨架实例结合在一起。这两个簇3均已通过X射线晶体学表征。
• Reactions of metalloalkynes VII. Protonation of ruthenium ethyne-1,2-diyl complexes
  作者：Christopher S. Griffith、George A. Koutsantonis、Brian W. Skelton、Allan H. White

  DOI：10.1016/s0022-328x(02)02196-4

  日期：2003.3

  The acid–base chemistry of some ruthenium ethyne-1,2-diyl complexes, [Ru(CO)2(η-C5H4R)}2(μ2-CC)] (R=H, Me) has been investigated. Initial protonation of [Ru(CO)2η-C5H4R}}2(μ2-CC)] gave the unexpected complex cation, crystallised as the BF4 salt, [Ru(CO)2(η-C5H4R}}3(μ3-CC)][BF4] (R=Me structurally characterised). This synthesis proved to be unreliable but subsequent, careful protonation experiments

  一些钌乙炔-1,2-二基配合物的酸-碱化学，[的Ru（CO）2（η-C 5 H ^ 4 R）} 2（μ 2 -CC）]（R = H，我）已被调查。的初始质子化[的Ru（CO）2 η-C 5 H ^ 4 R}} 2（μ 2 -CC）〕得到意想不到的复杂阳离子，结晶为BF 4盐，[的Ru（CO）2（η-C 5 H ^ 4 R}} 3（μ 3 -CC）] [BF 4]（R ＝ Me在结构上表征）。这种合成被证明是不可靠的，但随后，小心质子化实验，得到质子化乙炔-1,2-二基配合物的优异的产率，[的Ru（CO）2 η-C 5 H ^ 4 R）} 2（μ 2 -η 1：η 2 -CCH）]（BF 4）（R =我结构表征），可能在高收率返回起始乙炔-1,2-二基配合物去质子化。
• Transformation of C2 units on a bimetallic tetranuclear cluster.
  作者：Christopher S. Griffith、George A. Koutsantonis、Brian W. Skelton、Allan H. White

  DOI：10.1016/j.jorganchem.2005.04.023

  日期：2005.7

  The reactivity of [Ru3Mo(mu(4)-eta(2)-CC)(mu-CO)(3)(CO)(2)(eta-C5H4R)(3)(eta-C5H5)] (R = H; Me) have been investigated, initially to elucidate the nature of the starting material, and, latterly, to define the reactivity of an interesting ethane-1,2-bis(ylidyne) species. While the mixed RuMo clusters were unreactive towards simple electrophiles and carbonyl substitution by phosphine ligands they did react with atmospheric oxygen or carbon monoxide to give substantially different products. In all instances oxygen was incorporated either at the metal centre or at the C-2 fragment. High-pressure carbonylations yielded [Ru-3(mu-CO)(3)(eta-C5H5)(3)(mu(3)-C-C(O)ORu-(CO)(2)(eta-C5H5)})] and [Ru-2(mu-CO)(CO)(2)(eta-C5H4Me)(2)}(mu(4)-eta(2)-C=C)Ru(CO)(eta-C5H4Me)Mo(eta-C5H5)(=O)(mu-O)}], an ethane-1,2-bis(ylidene) complex, this exemplifying a relatively rare raft geometry which further reacted with Cl2C=CCl2 to give [Mo-3(mu(4)-C-4(Ru(CO)(2)(eta-C5H4Me))(CO)(mu-CO)(eta-C5H5)(3)(Cl)(2)] having a similar geometry and undergone halogenation. In order to extend the extant examples of these raft clusters we explored the reaction of [Ru(CO)(2)(eta-C5H4R)(2)}(2)(mu-C-2)] with [Ru(CO)(2)(eta-C5H5)(2)}(2)] to provide a rational synthetic pathway leading to very reactive [Ru(mu(4)-eta(2)-CC)(mu(2)-CO)(2)(CO)(4)(eta-C5H4Me)(2)(eta-C5H4R)(2)] rafts. (c) 2005 Elsevier B.V. All rights reserved.