1-phenylthio-3,4-dimethyl-3-arsolene pentacarbonylchromium | 160954-47-2

• 英文名称: 1-phenylthio-3,4-dimethyl-3-arsolene pentacarbonylchromium
• CAS: 160954-47-2
• 化学式: C₁₇H₁₅AsCrO₅S
• 分子量: 458.287
• InChiKey: LQGWDVWEYGNIQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (acetonitrile)pentacarbonylchromium 、 1-Phenylthio-3,4-dimethyl-3-arsolen 以 乙醇 为溶剂， 以68%的产率得到1-phenylthio-3,4-dimethyl-3-arsolene pentacarbonylchromium
  参考文献：
  名称：

  Reaktive Arsen-Heterocyclen

  摘要：

  3-Arsolenes R-As-CH2-C(Me)=C(R')-CH, (R = Ph, Me, (t)Bu, Cl, R' = H, Me) are readily obtained from zirconocene-butadiene complexes and RAsCl2. Alkylation with methyl iodide gives arsonium salts [R(Me)As-CH2-C(Me)=C(R')-CH2]I (R = Ph, Me, (t)Bu, R'= H, Me), treatment with sulphur gives sulphides R(S)As-CH2-C(Me)=C(Me)-CH, (R = Me, (t)Bu), while oxidation with Br, or SO2Cl2 results in ring cleavage. From chloroarsolene Cl-As-CH2-C(Me)=((Me)-CH2 substitution products R-As-CH2-C(Me)=C(Me)-CH2 (R = 1, H, SPh, OMe, NMe2) as well as coupling products with As-As, As-0-As, and As-S-As units were synthesized. In addition, a number of arsolene complexes with the metals chromium, molybdenum, tungsten, and ruthenium is described.

  DOI：

  10.1016/0022-328x(94)88008-5