[n-Bu4N][(cis-Mo(η3-methallyl)(CO)2(μ-Cl))2(μ-3,5-dimethylpyrazolate)] | 1384465-38-6

• 英文名称: [n-Bu4N][(cis-Mo(η3-methallyl)(CO)2(μ-Cl))2(μ-3,5-dimethylpyrazolate)]
• CAS: 1384465-38-6
• 化学式: C₁₆H₃₆N*C₁₇H₂₁Cl₂Mo₂N₂O₄
• 分子量: 822.619
• InChiKey: OALMYFQFODEROJ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡唑 、 tetra-n-butylammonium hydroxide 、 [Mo(η3-methallyl)Cl(CO)2(acetonitrile)2] 以 四氢呋喃 、 水 为溶剂， 以91%的产率得到[n-Bu4N][(cis-Mo(η3-methallyl)(CO)2(μ-Cl))2(μ-3,5-dimethylpyrazolate)]
  参考文献：
  名称：

  Triple bridged anionic dimetallic complexes from cis-[Mo(η3-methallyl)Cl(CO)2(NCMe)2] and pyrazolates

  摘要：

  The reactions of cis-[Mo(eta(3)-methallyl)Cl(CO)(2)(NCMe)(2)] and 0.5 equivalents of tetra-n-butylammonium salts of pyrazolate (pz), 3,5-dimethylpyrazolate (dmpz) or indazolate (inz) lead to (NBu4)-Bu-n[{Mo(eta(3)-methallyl)(CO)(2)(mu-Cl)}(2)(mu-pz*)] (pz* = pz, dmpz, inz), where the bridging pyrazolato is coordinated trans to the allyl group and both bridging chlorido ligands are coordinated trans to the carbonyls. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.04.021