| 1443246-47-6

• CAS: 1443246-47-6
• 化学式: C₁₃H₁₈AuCl₃N₄
• 分子量: 533.638
• InChiKey: QBJYTTHNIFRLMY-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium tetrachloroaurate(III) dihydrate 、 以 丙酮 为溶剂， 反应 6.0h， 生成
  参考文献：
  名称：

  Synthesis and characterization of novel gold(III) complexes with polydentate N-donor ligands based on the pyridine and triazole heterocycles

  摘要：

  The coordination chemistry towards the Au(III) metal centre of the pyridine-triazole ligands 2-[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine (pytz(Ph)) and 2-[(4-pentyl-1H-1,2,3-triazol-1-yl)methyl]pyridine (pytz(Pent))has been explored and complexes having formulae AuCl3(pytz(Ph)) (1(Ph)) and AuCl3(pytz(Pent)) (1(Pent)) have been isolated and characterised. Reaction of 1(Ph) with AgClO4 allowed the preparation of the compound [AuCl2(pytz(Ph))](ClO4) (2(Ph)). Reaction of 1(Ph) and 1(Pent) with K[AuCl4]center dot 2H(2)O led to the formation of the salts [Hpytz(Ph)][AuCl4] (3(Ph)) and [Hpytz(Pent)][AuCl4] (3(Pent)). (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.04.015
• 作为产物：
  描述：

  potassium tetrachloroaurate(III) dihydrate 、 2-[(4-pentyl-1H-1,2,3-triazol-1-yl)methyl]pyridine 以 甲醇 、 水 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of novel gold(III) complexes with polydentate N-donor ligands based on the pyridine and triazole heterocycles

  摘要：

  The coordination chemistry towards the Au(III) metal centre of the pyridine-triazole ligands 2-[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine (pytz(Ph)) and 2-[(4-pentyl-1H-1,2,3-triazol-1-yl)methyl]pyridine (pytz(Pent))has been explored and complexes having formulae AuCl3(pytz(Ph)) (1(Ph)) and AuCl3(pytz(Pent)) (1(Pent)) have been isolated and characterised. Reaction of 1(Ph) with AgClO4 allowed the preparation of the compound [AuCl2(pytz(Ph))](ClO4) (2(Ph)). Reaction of 1(Ph) and 1(Pent) with K[AuCl4]center dot 2H(2)O led to the formation of the salts [Hpytz(Ph)][AuCl4] (3(Ph)) and [Hpytz(Pent)][AuCl4] (3(Pent)). (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.04.015