[Cu3(diethylenetriamine)2(azide)6] | 702687-65-8

• 英文名称: [Cu3(diethylenetriamine)2(azide)6]
• CAS: 702687-65-8
• 化学式: C₈H₂₆Cu₃N₂₄
• 分子量: 649.093
• InChiKey: CTOGAEWAVHBPQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二乙烯三胺 、 copper diacetate 、 sodium azide 以 乙醇 、 水 为溶剂， 以17%的产率得到[Cu3(diethylenetriamine)2(azide)6]
  参考文献：
  名称：

  Synthesis and characterization of copper(II) azide complexes containing polyamines as co-ligands

  摘要：

  Two new copper(II) azide complexes Cu-2(pn)(2)(N-3)(4) (1) and Cu-3(dien)(2)(N-3)(6) (2) (pn = 1,3-diaminopropane and then = diethylenetriamine) have been synthesized and characterized by single crystal X-ray diffraction. In complex I each copper(II) atom is coordinated to six nitrogen atoms from four azide anions and one 1,3-diaminopropane molecule in a distorted octahedral geometry. Successive pairs of copper(II) atoms are linked by two end-on azide bridges to form a polymeric chain. In centrosymmetric complex 2 the central copper(II) is coordinated by two monodentate azide anions and linked to two terminal copper atoms by double end-on azide bridges to give a linear trinuclear unit. The coordination geometry around each of the terminal copper atoms is square pyramidal, being surrounded by two nitrogen atoms of the bridging azide anions and three nitrogen atoms of the diethylenetriamine ligand. Magnetic susceptibility measurement of complex 2 in the range 2-300 K showed weak antiferromagnetic exchange between the copper(II) ions (J = -2.09(8) cm(-1)) through the double end-on azide bridges. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.02.003