[Fe(η-Cp)(η-9,10-dihydroanthracene)][PF6] | 59236-70-3

• 英文名称: [Fe(η-Cp)(η-9,10-dihydroanthracene)][PF6]
• CAS: 59236-70-3
• 化学式: C₁₉H₁₇Fe*F₆P
• 分子量: 446.155
• InChiKey: SBXYGMBDHNKMQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Fe(η-Cp)(η-9,10-dihydroanthracene)][PF6] 、 三甲氧基磷 以 乙腈 为溶剂， 以85%的产率得到{(η5-cyclopentadienyl)Fe(P(OMe3)3)}PF6
  参考文献：
  名称：

  Electron transfer catalysis of arene deco-ordination in the cationic (η⁵-cyclopentadienyl)(η⁶-arene)iron(II) complexes

  摘要：

  在温和条件下，通过在乙腈中进行还原电子转移催化，将[Fe(η⁵-C₅H₅)(η⁶-C₆H₆–n-Men)]+(n≤4)中的芳香基团置换为三个P(OMe)₃配体，所得产物为游离芳香烃和[(η⁵-C₅H₅)Fe {P(OMe)₃}₃]+，产率良好。

  DOI：

  10.1039/c39830000768
• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 蒽 、 二茂铁 在 三氯化铝 、 氢化铝 作用下， 以 水 为溶剂， 以5%的产率得到[Fe(η-Cp)(η-9,10-dihydroanthracene)][PF6]
  参考文献：
  名称：

  Synthesis and decomplexation of (η-arene)(η-cyclopentadienyl)-iron(II) hexafluorophosphates using microwave dielectric heating

  摘要：

  A detailed study of the synthesis of (eta-arene)(eta-cyclopentadienyl)iron(II) hexafluorophosphates has been made using microwave dielectric heating. Reactions were carried out in a conventional 850 W microwave oven in a very simple solid CO2-cooled apparatus. A wide range of arene ligands were used. The microwave technique reduced the normal reaction times for the AlCl3-mediated ligand exchange with ferrocene (with aluminium powder to prevent ferricinium ion formation) from several hours to a few minutes and generally resulted in higher yields. 1,2,4-Trichlorobenzene was found to be an excellent solvent for such reactions. A preliminary survey of the efficacy of the type of the metal powder used revealed that zinc and copper were as effective as aluminium, but that nickel and tin gave little or no reaction. Better yields were usually obtained when an excess of ferrocene was used. This was particularly true of alkylarene ligands where almost quantitative yields were obtained in some cases. The microwave method is particularly suited to the synthesis of bis and more highly complexed species. Arylamine complexes can also be made in high yields. Complexes of triphenylphosphine are reported together with a wide range of other arenes.Decomplexation of these complexes can be efficiently achieved by a slight variant of the above microwave procedure. High yields of free ligand were obtained by irradiating an admixture of the complexes with flaked graphite.

  DOI：

  10.1039/p19950000743