trichlor tripyridine iron (III) (monopyridine) | 84276-94-8

• 英文名称: trichlor tripyridine iron (III) (monopyridine)
• CAS: 84276-94-8
• 化学式: C₅H₅N*C₁₅H₁₅Cl₃FeN₃
• 分子量: 478.612
• InChiKey: GQYRJHIQSPWHAM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三氯化铁 在 pyridine 作用下， 以 吡啶 为溶剂， 生成 trichlor tripyridine iron (III) (monopyridine)
  参考文献：
  名称：

  吡啶鎓μ-氧代-双[三铁高铁酸盐（III）]-吡啶的晶体和分子结构及某些性质

  摘要：

  确定了标题化合物[Hpy] 2 [Cl 3 Fe–O–FeCl 3 ]·py的晶体结构，该化合物通过FeCl 3在乙醇-吡啶水溶液中的水解而制备。晶体是单斜晶体，其中a = 8.532（6），b = 13.914（11），c = 10.597（11）Å，β= 110.8（1）°，Z = 2和空间群P 2 1 / m。该结构已通过Patterson和Fourier方法进行了解析，并通过全矩阵最小二乘法将衍射仪测得的1 236次独立的背景以上反射的R最小化为R 0.056。在晶体学上施加C的络合物阴离子中按照对称性，两个等效的FeOCl 3单元通过短的Fe–O键[1.755（3）Å]与氧原子桥接，Fe–O–Fe角为155.6（7）°。每种金属的几何形状都接近四面体，Cl–Fe–Cl和Cl–Fe–O角度为108–111°。与[FeCl 4 ] –中的距离相比，Fe–Cl的距离（2.208–2.2

  DOI：

  10.1039/dt9780000080

文献信息

• FeCl 2 py 4 + catalyzed transformation of aromatic amines by HOOH under mild conditions
  作者：Miquel Costas、Isabel Romero、Ma.Angeles Martı́nez、Antoni Llobet、Donald T. Sawyer、Josep Caixach

  DOI：10.1016/s1381-1169(99)00057-6

  日期：1999.12

  FeCl(2)py(4)(+) is capable of activating HOOH for the selective and efficient (yields range roughly from 50 to 80%) transformation of anilines at room temperature using pyridine as the solvent. Initially, aniline yields mainly nitrosobenzene that in turn reacts with more aniline to form the corresponding azo and azoxybenzene derivatives. Replacing HOOH by t-BuOOH in the system, changes the product distribution dramatically forming only nitrobenzene. Under the same conditions FeCl(2)py(4)(+) efficiently catalyzes the mono-demethylation of N,N'-dimethylaniline by HOOH. (C) 1999 Elsevier Science B.V. All rights reserved.
• Hoser, Andrzej; Kaluski, Zygmunt; Januszczyk, Michal, Acta Crystallographica, Section C: Crystal Structure Communications, 1983, vol. 39, p. 1039 - 1041
  作者：Hoser, Andrzej、Kaluski, Zygmunt、Januszczyk, Michal、Pietrzak, Jerzy、Glowiak, Tadeusz

  DOI：——

  日期：——
• Synthesis and Mössbauer effect studies of low dimensional organoiron compound Fe(py)3Cl3·py
  作者：M. Januszczyk、J. Janicki、H. Wojakowska、R. Krzyminiewski、J. Pietrzak

  DOI：10.1016/s0020-1693(00)87926-8

  日期：1991.8

  The Fe(py)3Cl3.py complexes (where py is the pyridine molecule) of iron(III) have been prepared by the reaction of anhydrous ferric chloride with pyridine. Crystals of Fe(py)3Cl3.py may occur in two crystallographic systems: orthorhombic and monoclinic with the structural phase transition at a temperature close to 200 K. The obtained Mossbauer parameters of these complexes provide the possibility to determine the pyridine stoichiometry, electron spin and oxidation states of iron in single crystals.