[(2,14-dimethyl-3,6,10,13,19-pentaazabicyclo[13.3.1]nonadeca-1(19),2,13,15,17-pentaene)dichlorolutetium(III)] perchlorate | 637743-72-7

• 英文名称: [(2,14-dimethyl-3,6,10,13,19-pentaazabicyclo[13.3.1]nonadeca-1(19),2,13,15,17-pentaene)dichlorolutetium(III)] perchlorate
• CAS: 637743-72-7
• 化学式: C₁₆H₂₅Cl₂LuN₅*ClO₄
• 分子量: 632.732
• InChiKey: YJLRIVHZDVSSLB-DRLFUFNGSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N'-二(2-氨乙基)-1,3-丙二胺 、 2,6-二乙酰基吡啶 、 lutetium(III) chloride hexahydrate 、 lutetium(III) perchlorate hydrate 以 甲醇 为溶剂， 以87%的产率得到[(2,14-dimethyl-3,6,10,13,19-pentaazabicyclo[13.3.1]nonadeca-1(19),2,13,15,17-pentaene)dichlorolutetium(III)] perchlorate
  参考文献：
  名称：

  The template synthesis and characterization of pentaaza macrocyclic complexes of rare earth elements. The crystal structure of the 2,14-dimethyl-3,6,10,13,19-pentaazabicyclo[13.3.1]nonadeca-1(19),2,13,15,17-pentaene-dichlorolutetium(III)perchlorate

  摘要：

  The yttrium and lanthanide ions were found to act as templates for the cyclic [1 + 1] condensation of 2,6-diacetylpyridine with 3,7diazanonane-1,9-diamine to yield 16-membered pentadentate Schiff base macrocyclic complexes with an N-5 set of donor atoms. The complexes were characterized by spectral data (IR, luminescence, H-1 NMR, FAB MS) and elemental analysis. The crystal structure of the lutetium complex was determined by single X-ray analysis providing the first example of the seven-coordination and pentagonal bipyramidal coordination geometry found among the lutetium macrocyclic compounds. (C) 2003 Published by Elsevier Ltd.

  DOI：

  10.1016/s0277-5387(03)00398-x