| 123712-12-9

• CAS: 123712-12-9
• 化学式: C₂₅H₃₈ClFeOP₃S
• 分子量: 570.863
• InChiKey: CYHXJUINCHDXEZ-NKCJSPSGSA-L

反应信息

• 作为反应物：
  描述：

  、 四苯硼钠 、 乙腈 以 甲醇 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Intramolecular coupling reaction of phosphino–thioenolato iron(II) complexes with alkynes. Crystal structure of [Fe{η³-Ph₂P–CHC(Bu^t)S–CCHPh}(CO)(PMe₃)₂]BF₄

  摘要：

  [FeCl{η2-Ph2PCHC(R)S}(PMe3)(CO)(L)] complexes, prepared by ligand substitution, react with phenylacetylene in the presence of AgBF4 or NaPF6 and lead to carbon–sulphur bond formation between the β-phosphino–thioenolate ligand and the phenylvinylidene–iron intermediate, as shown by X-ray diffraction analysis.

  DOI：

  10.1039/c39880001408
• 作为产物：
  描述：

  、 三甲基膦 以 二氯甲烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Intramolecular coupling reaction of phosphino–thioenolato iron(II) complexes with alkynes. Crystal structure of [Fe{η³-Ph₂P–CHC(Bu^t)S–CCHPh}(CO)(PMe₃)₂]BF₄

  摘要：

  [FeCl{η2-Ph2PCHC(R)S}(PMe3)(CO)(L)] complexes, prepared by ligand substitution, react with phenylacetylene in the presence of AgBF4 or NaPF6 and lead to carbon–sulphur bond formation between the β-phosphino–thioenolate ligand and the phenylvinylidene–iron intermediate, as shown by X-ray diffraction analysis.

  DOI：

  10.1039/c39880001408