1,3-bis[(2,4,6-trimethylphenylimino)benzyl]imidazolium tetrafluoroborate | 1231760-48-7

• 英文名称: 1,3-bis[(2,4,6-trimethylphenylimino)benzyl]imidazolium tetrafluoroborate
• CAS: 1231760-48-7
• 化学式: BF₄*C₃₅H₃₅N₄
• 分子量: 598.494
• InChiKey: IZHLJYJZMJQQBJ-KTLQDXEESA-N

反应信息

• 作为反应物：
  描述：

  copper(l) iodide 、 1,3-bis[(2,4,6-trimethylphenylimino)benzyl]imidazolium tetrafluoroborate 在 sodium bis(trimethylsilyl)amide 作用下， 以 四氢呋喃 为溶剂， 以61%的产率得到1,3-bis[(2,4,6-trimethylphenylimino)benzyl]imidazol-2-ylidene copper(I) iodide
  参考文献：
  名称：

  Synthesis and Structural Characterization of the First Copper(I) Complexes with Bis(imino)-N-heterocyclic Carbene NCN Pincer Ligands

  摘要：

  A new class of bis(acyclic imino)-N-heterocyclic carbene (NCN pincer) ligand precursors was synthesized and structurally characterized. In situ deprotonation using a basic metal precursor resulted in the corresponding copper(I) complexes in good yields. Monometallic and bimetallic structures were observed in the solid state depending on the ligand substitution pattern.

  DOI：

  10.1021/om100321n