mer-[RhCl3(bis(trimethylsilylmethyl)tellane)3] | 1150104-19-0

• 英文名称: mer-[RhCl3(bis(trimethylsilylmethyl)tellane)3]
• CAS: 1150104-19-0
• 化学式: C₂₄H₆₆Cl₃RhSi₆Te₃
• 分子量: 1115.37
• InChiKey: VPNSVUARZFGDLI-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氯化铑(三水) 、 Bis<(trimethylsilyl)methyl>telluran 以 乙醇 为溶剂， 以79%的产率得到mer-[RhCl3(bis(trimethylsilylmethyl)tellane)3]
  参考文献：
  名称：

  Versatile coordination chemistry of rhodium complexes containing the bis(trimethylsilylmethyl)tellane ligand

  摘要：

  When RhCl3 center dot 3H(2)O was treated with an excess of Te(CH2SiMe3)(2), a mononuclear mer-[RhCl3{Te(CH2SiMe3)(2)}(3)] (1) was observed as the main product. By reducing the metal-to-ligand molar ratio, dinuclear [Rh-2(mu-Cl)(2)Cl-4{Te(CH2SiMe3)(2)}(4)] (2) was obtained in addition to 1. Further reduction of the metal-to-ligand ratio resulted in the formation of [Rh-2(mu-Cl)(2)Cl-4(OHCH2CH3){Te(CH2SiMe3)(2)}(3)] (3). The treatment of mer-[RhCl3(SMePh)(3)] (4) with two equivalents of Te(CH2SiMe3)(2) affords a mixture of mer[RhCl3{Te(CH2SiMe3)(2)}(3)] (1) and mer-[RhCl3{Te(CH2SiMe3)(2)}(2)(SMePh)] (5). All complexes 1-4 and 5 center dot 1/2EtOH were characterized by X-ray crystallography and Te-125 NMR spectroscopy, where appropriate. The definite assignment of the Te-125 chemical shifts enabled a plausible discussion of the assignment of some unknown resonances that were observed in the NMR spectra. (c) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.02.001