HC(CMeN-2,6-i-Pr₂C₆H₃)₂Al[(μ-N)(μ-S)](o-C₆H₄) | 1393577-36-0

• 英文名称: HC(CMeN-2,6-i-Pr₂C₆H₃)₂Al[(μ-N)(μ-S)](o-C₆H₄)
• CAS: 1393577-36-0
• 化学式: C₃₅H₄₅AlN₃S
• 分子量: 566.81
• InChiKey: FPPIYTBNQNZTPM-GGFZQTNZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(HC(CMeN(2,6-i-Pr2C6H3))2)AlH2] 、 2-氨基苯硫醇 以 四氢呋喃 为溶剂， 生成 HC(CMeN-2,6-i-Pr₂C₆H₃)₂Al[(μ-N)(μ-S)](o-C₆H₄)
  参考文献：
  名称：

  Reactivity Studies of LAlH₂ (L = HC(CMeNAr)₂, Ar = 2,6-iPr₂C₆H₃) with 2-Aminobenzenethiol, 2-Aminophenol, and 1,4-Dithiane-2,5-diol

  摘要：

  The reaction of LAlH2 (L = HC(CMeNAr)(2), Ar = 2,6-iPr(2)C(6)H(3)) (1) with 2-aminobenzenethiol, 2-aminophenol, and 1,4-dithiane-2,5-diol resulted in the compounds LAl[(mu-N)(mu-S)(o-C6H4) (2), LAl[(mu-O)(o-C6H4)(NH2)](2) (3), and LAl(mu-O)(2)(p-dithiane) (4), respectively. Compound 2 features an organic-inorganic hybrid containing an NAlSC2 five-membered ring, while compound 3 exhibits a C-O-Al-O-C chain structure. Compound 4 forms a basket-like molecule with the C4S2 unit as the bottom part and O2Al as the handle. Complexes 2, 3, and 4 were characterized by H-1 NMR, elemental analysis, and single-crystal X-ray diffraction studies.

  DOI：

  10.1021/om300577j