| 151709-47-6

• CAS: 151709-47-6
• 化学式: C₃₁H₂₃ClN₅Ru*F₆P
• 分子量: 747.044
• InChiKey: CSXQKNSMGRCJDN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 水 为溶剂， 以0%的产率得到(6-phenyl-2,2'-bipyridine(1-))(2,2':6',2''-terpyridine)ruthenium(II) hexafluorophosphate
  参考文献：
  名称：

  Solvent effects in the reactions of 6-phenyl-2,2′-bipyridine with ruthenium(II)

  摘要：

  The reaction of [Ru(tpy)Cl3] with the potentially cyclometallating ligand 6-phenyl-2,2'-bipyridine (HL) has been examined in a variety of solvents. In glacial acetic acid the ligand acts as a substituted 2,2'-bipyridine and reacts to give the complex cation [Ru(tpy)(HL)Cl]+, containing a bidentate N,N'-bonded HL ligand. The structure of this complex has been unambiguously established from its H-1 NMR spectrum. In contrast, the use of water as a solvent gives the cyclometallated complex cation [Ru(tpy)(L)]+. In methanol and butan-1-ol, mixtures of these two products are formed. The work has been extended to 2,2':6',2''-terpyridines with aromatic substituents in the 4' position and the complexes have been characterised by H-1 NMR, electronic and FAB mass spectroscopic techniques and also by cyclic voltammetry.

  DOI：

  10.1016/s0020-1693(00)82850-9
• 作为产物：
  描述：

  (6-phenyl-2,2'-bipyridine(1-))(2,2':6',2''-terpyridine)ruthenium(II) hexafluorophosphate 以 溶剂黄146 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  Solvent effects in the reactions of 6-phenyl-2,2′-bipyridine with ruthenium(II)

  摘要：

  The reaction of [Ru(tpy)Cl3] with the potentially cyclometallating ligand 6-phenyl-2,2'-bipyridine (HL) has been examined in a variety of solvents. In glacial acetic acid the ligand acts as a substituted 2,2'-bipyridine and reacts to give the complex cation [Ru(tpy)(HL)Cl]+, containing a bidentate N,N'-bonded HL ligand. The structure of this complex has been unambiguously established from its H-1 NMR spectrum. In contrast, the use of water as a solvent gives the cyclometallated complex cation [Ru(tpy)(L)]+. In methanol and butan-1-ol, mixtures of these two products are formed. The work has been extended to 2,2':6',2''-terpyridines with aromatic substituents in the 4' position and the complexes have been characterised by H-1 NMR, electronic and FAB mass spectroscopic techniques and also by cyclic voltammetry.

  DOI：

  10.1016/s0020-1693(00)82850-9

文献信息

• Reversible cyclometallation at a ruthenium(II) centre
  作者：Edwin C. Constable、Simon J. Dunne、David G. F. Rees、Chantal X. Schmitt

  DOI：10.1039/cc9960001169

  日期：——

  The metallated complex [Ru(tbp)(tpy)][PF6][Htbp = 6-(2-thienyl)-2,2′-bipyridine, tpy = 2,2′:6′,2″-terpyridine] is converted to the non-metallated species [Ru(Htbp)(tpy)][PF6] containing an N,N,S-bonded Htbp ligand upon treatment with acid; this process is reversed upon reaction of [Ru(Htbp)(tpy)][PF6] with aqueous sodium hydroxide solution.

  金属络合物[Ru(tbp)(tpy)][PF6][Htbp = 6-(2-噻吩基)-2,2′-联吡啶，tpy = 2,2′:6′,2″-三联吡啶]在酸处理后转化为非金属络合物[Ru(Htbp)(tpy)][PF6]，其中含有N,N,S键合的Htbp配体；当[Ru(Htbp)(tpy)][PF6]与氢氧化钠水溶液反应时，该过程可逆。