| 934165-47-6

• CAS: 934165-47-6
• 化学式: C₂₂H₂₄Cl₂N₂O₄Pt
• 分子量: 652.382
• InChiKey: VZFRLALAMNHOGF-HEFOIBTJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium trichloro(ethylene)platinate(II) 、 氘代甲醇 、 2-N,3-N-bis(2,6-dimethylphenyl)-1,1,1,4,4,4-hexafluorobutane-2,3-diimine 以 氘代甲醇 为溶剂， 以44%的产率得到
  参考文献：
  名称：

  Synthesis and Structural Characterization of a Fluorinated α-Diimine Platinum(II) Complex

  摘要：

  The preparation of an electron-deficient (N-N)PtCl2 complex in which the diimine C is substituted by CF3 is described. Thus, reactions between the diimine ligand 1 (R = CF3, R' = 2,6-dimethylphenyl) and PtCl2 (thermal reaction) or KPtCl3(C2H4) (photochemically activated) furnishes the corresponding (N-N)PtCl2 complex 2. The ligand 1 and its Pt complexes 2, as well as related (N-N)PtCl2 complexes 3 (R = CO2CD3, R' = 2,6-dimethylphenyl; a methanolysis product) and 4 (R = H, R' = 2,6-dimethylphenyl) have been characterized by X-ray crystallography.

  DOI：

  10.1021/om060897u