| 437711-99-4

• CAS: 437711-99-4
• 化学式: C₄₁H₃₇BO₂P₂Pd
• 分子量: 740.922
• InChiKey: SSTYAFRHIAHLAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [PdMe2((PPh2CH2)2BPh2)][5-azonia-spiro[4,4]nonane] 在 [HNEt(CH(CH₃)2)2][BPh₄] 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Catalytic Copolymerization of CO and Ethylene with a Charge Neutral Palladium(II) Zwitterion

  摘要：

  The synthesis of a zwitterionic Pd(II) complex supported by an anionic bis(phosphino)borate ligand, Ph(2)B(CH(2)PPh(2))(2) (abbreviated as [Ph(2)BP(2)]), is reported. The new complex, [Ph(2)BP(2)]PdMe(THF), is active for CO and ethylene copolymerization. The copolymerization activity and polyketone molecular weight for the neutral, zwitterionic system are compared with those for the cationic systems [R(2)E(CH(2)PPh(2))(2)PdMe(THF)][B(C(6)F(5))(4)] where ER(2) = SiPh(2) and CH(2). Surprisingly, the more electron rich zwitterionic system is a catalyst of activity comparable to that of the more conventional cationic systems.

  DOI：

  10.1021/ja017011s