| 245493-82-7

• CAS: 245493-82-7
• 化学式: NOP
• 分子量: 61.9732
• InChiKey: XISXEABRPCPPBM-OUBTZVSYSA-N

反应信息

• 作为产物：
  描述：

  diphosphoryl azide 以 solid matrix 为溶剂， 生成 、 、
  参考文献：
  名称：

  Elusive O═P≡N, a Rare Example of Phosphorus σ²λ⁵-Coordination

  摘要：

  Two linear isomers, OPN and ONP, were formed in an Ar matrix at 16 K by ArF laser (lambda = 193 nm) photolysis of phosphoryl triazide, OP(N-3)(3), and comprehensively characterized by their mid- and far-IR spectra as well as N-14/15 isotopic data. Two intermediates, (N-3)(2)P(O)N and N3P(O)N-4, have been isolated in an Ar matrix and spectroscopically characterized. Photolysis of these intermediates using near-LTV/vis light (lambda > 320 rim) was shown to yield exclusively ONP, which under ArF laser irradiation selectively photo-isomerized to OPN. The photochemical and molecular properties of OPN and ONP are discussed on the basis of experimental and ab initio calculated results.

  DOI：

  10.1021/ja2091867