[MoI(CO)3(η5-P3C2(tBu)2)] | 1143620-94-3

• 英文名称: [MoI(CO)3(η5-P3C2(tBu)2)]
• CAS: 1143620-94-3
• 化学式: C₁₃H₁₈IMoO₃P₃
• 分子量: 538.05
• InChiKey: WXTSJBRYLLTODN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  碘 、 molybdenum hexacarbonyl 、 potassium 3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl 以 N,N-二甲基甲酰胺 为溶剂， 以69%的产率得到[MoI(CO)3(η5-P3C2(tBu)2)]
  参考文献：
  名称：

  New phospholyl complexes of groups 4 and 6: Syntheses, characterisation and polymerisation studies

  摘要：

  [M((P3C2Bu2)-Bu-t)(CO)(3)I] (M = Mo, 1, W, 2) have been synthesised and reacted with PCl5 for oxidation study purposes. Compounds Ti((P3C2Bu2)-Bu-t)(Ind)Cl-2], 3, and [Zr((P3C2Bu2)-Bu-t)(Cp)Cl-2], 4, were detected spectroscopically, but showed to be too unstable to be isolated. A Ti(IV) complex, [Ti((P3C2Bu2)-Bu-t)Cl-3], 5, has been formed from the reaction of [TiCl4] with the base-free ligand K((P3C2Bu2)-Bu-t), while the Ti(III) species, [Ti((P3C2Bu2)-Bu-t) Cl-2(THF)], 6, was prepared from [TiCl3(THF)(3)]. Compounds 5 and 6 were studied as ethylene catalyst precursors after activation with MAO. In the studied conditions, complex 5 is the most active one with an activity of 2.2 x 10(5) g(molTi [E] h) (1), one order of magnitude higher than compound 6. The produced polymer is linear polyethylene. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.06.019