(4-methyl-N-(2-(diphenylphosphino)phenyl)-2-(1H-pyrazol-1-yl)benzenamine(-1H))Rh(CO) | 1432670-61-5

• 英文名称: (4-methyl-N-(2-(diphenylphosphino)phenyl)-2-(1H-pyrazol-1-yl)benzenamine(-1H))Rh(CO)
• CAS: 1432670-61-5
• 化学式: C₂₉H₂₃N₃OPRh
• 分子量: 563.4
• InChiKey: GQMNKLCEFGCSDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  异氰酸叔丁酯 、 (4-methyl-N-(2-(diphenylphosphino)phenyl)-2-(1H-pyrazol-1-yl)benzenamine(-1H))Rh(CO) 以 丙酮 为溶剂， 反应 2.0h， 以87%的产率得到κ²PN-(4-methyl-N-(2-(diphenylphosphino)phenyl)-2-(1H-pyrazol-1-yl)benzenamine(-1H))Rh(tert-butyl isocyanide)₂
  参考文献：
  名称：

  Rhodium Complexes of a New Structurally Adaptive PNN-Pincer Type Ligand

  摘要：

  A new PNN-pincer type ligand with pyrazolyl and diphenylphosphine flanking donors on a diarylamido anchor has been prepared. Its bis(tert-butyl isocyanide)rhodium(I) complex exhibits hemilabile behavior in solution, and its solid-state structure verified the elusive (KP)-P-2,N coordination mode for this type of ligand. Reactions between (PNN)Rh((CNBu)-Bu-t)(2) and iodomethane afford both fac- and cis,mer-[(PNN)Rh((CNBu)-Bu-t)(2)(Me)RI), which further showcases the structural versatility of the ligand.

  DOI：

  10.1021/om400151e
• 作为产物：
  描述：

  2-iodo-N-(4-methyl-2-(1H-pyrazol-1-yl)phenyl)benzenamine 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三乙胺 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 作用下， 以 1,4-二氧六环 、 丙酮 为溶剂， 反应 15.25h， 生成 (4-methyl-N-(2-(diphenylphosphino)phenyl)-2-(1H-pyrazol-1-yl)benzenamine(-1H))Rh(CO)
  参考文献：
  名称：

  Rhodium Complexes of a New Structurally Adaptive PNN-Pincer Type Ligand

  摘要：

  A new PNN-pincer type ligand with pyrazolyl and diphenylphosphine flanking donors on a diarylamido anchor has been prepared. Its bis(tert-butyl isocyanide)rhodium(I) complex exhibits hemilabile behavior in solution, and its solid-state structure verified the elusive (KP)-P-2,N coordination mode for this type of ligand. Reactions between (PNN)Rh((CNBu)-Bu-t)(2) and iodomethane afford both fac- and cis,mer-[(PNN)Rh((CNBu)-Bu-t)(2)(Me)RI), which further showcases the structural versatility of the ligand.

  DOI：

  10.1021/om400151e