[Au(III)(2,9-dimethyl-1,10-phenanthroline)Cl2]ClO4 | 917249-10-6

• 英文名称: [Au(III)(2,9-dimethyl-1,10-phenanthroline)Cl2]ClO4
• CAS: 917249-10-6
• 化学式: C₁₄H₁₂AuCl₂N₂*ClO₄
• 分子量: 575.586
• InChiKey: ZREZZTGKQYKVEA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloroauric acid 、 新铜试剂 、 sodium perchlorate 以 乙腈 为溶剂， 以68%的产率得到[Au(III)(2,9-dimethyl-1,10-phenanthroline)Cl2]ClO4
  参考文献：
  名称：

  Effect of heterocyclic diimine ligands with donor and acceptor substituents on the spectroscopic and electrochemical properties of Au(III) complexes

  摘要：

  The composition, structure, and properties of a series of Au(III) complexes with heterocyclic diimine ligands [Au(N<^>N)Cl-2)](+), where (N<^>N) = 2,2'-bipyridine (Bipy), 4,4'-dimethyl-2,2'-bipyridine (DmBipy), 2,2'-biquinoline (Bqx), 1,10-phenanthroline (Phen), 2,9-dimethyl-1,10-phenanthroline (DmPhen), and 4,7-diphenyl-1,10-phenanthroline (DphPhen), were characterized by H-1 NMR, electronic absorption, and emission spectroscopy and also by cyclic voltammetry. The influence of donor and acceptor substituents on the spectroscopic and electrochemical properties of the Au(III) complexes was revealed.

  DOI：

  10.1134/s1070363206020010