{RhCu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)} | 135157-54-9

• 英文名称: {RhCu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)}
• CAS: 135157-54-9
• 化学式: C₄₁H₄₅B₉CuOP₂Rh
• 分子量: 879.506
• InChiKey: IGZZNRBBSCQOPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (triphenylphosphine)CuCl 、 {N(C2H5)4}{Rh(CO)(P(C6H5)3)(η5-C2B9H9(CH3)2)} 在 TlBF₄ 作用下， 以 二氯甲烷 为溶剂， 以55%的产率得到{RhCu(CO)(P(C6H5)3)2(η5-C2B9H9(CH3)2)}
  参考文献：
  名称：

  Carbaboranerhodium complexes with Rh–Rh, Rh–Cu and Rh–Au bonds; crystal structure of [NEt₄][Rh₂(µ-σ : η⁵-C₂B₉H₈Me₂)(CO)₃(η⁵-C₂B₉H₉Me₂)]

  摘要：

  The compound [NEt4][Rh(CO)(PPh3)(eta-5-C2B9H9Me2)] has been prepared and used to synthesise the dimetal complexes [RhM(CO)(PPh3)2(eta-5-C2B9H9Me2)] (M = Cu or Au) and [RhCu(CO)(PMe3)(PPh3)(eta-5-C2B9H9Me2)]. Protonation of [NEt4][Rh(CO)(PPh3)(eta-5-C2B9H9Me2)] gives an unstable hydride [RhH(CO)(PPh3)(eta-5-C2B9H9Me2)]. In contrast, treatment of [NEt4][Rh(CO)2(eta-5-C2B9H9Me2)] with HBF4.Et2O affords a dirhodium complex [Rh2(CO)3(eta-5-C2B9H9Me2)2] in which one carbaborane fragment bridges the Rh-Rh bond via an exopolyhedral B-H half-arrow-pointing-right Rh bond. This species can be deprotonated to give an anionic complex [Rh2(mu-sigma:eta-5-C2B9H8Me2)(CO)3(eta-5-C2B9H9Me2)]-, the [NEt4]+ salt of which may be obtained directly from [NEt4][Rh(CO)2(eta-5-C2B9H9Me2)] by treatment of the latter with [NHMe3]Cl. An X-ray crystallographic study established the structure of the anion. One rhodium centre is ligated by a CO molecule and by a C2B9H9Me2 cage in the normal eta-5 bonding mode, the other carries two CO groups and an eta-5-C2B9 cage. However, a boron atom beta to the carbons in the pentagonal open activated CCBBB face of this cage forms a sigma bond to the other rhodium atom [B-Rh 2.05(3) angstrom], so that this C2B9H9Me2 group bridges the Rh-Rh bond [2.876(3) angstrom]. The NMR data for the new compounds are reported and discussed.

  DOI：

  10.1039/dt9910001355