chloro(2,2'-dimethyl-4,4'-bithiazole)(isophthalato(1-))copper(II) | 1245210-40-5

• 英文名称: chloro(2,2'-dimethyl-4,4'-bithiazole)(isophthalato(1-))copper(II)
• CAS: 1245210-40-5
• 化学式: C₁₆H₁₃ClCuN₂O₄S₂
• 分子量: 460.421
• InChiKey: FSZDCMSUESZNQZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-dimethyl-4,4'-bithiazole 、 copper(II) choride dihydrate 、 间苯二甲酸 在 ethylene diamine 作用下， 以 甲醇 、 水 为溶剂， 以67.4%的产率得到chloro(2,2'-dimethyl-4,4'-bithiazole)(isophthalato(1-))copper(II)
  参考文献：
  名称：

  Monomer and cyclic tetramer of copper(II) complexes: Synthesis, characterization and crystal structure determination of [Cu(dm4bt)Cl(Hipht)] and [{Cu(dm4bt)(H2O)(ipht)}4·2H2O]

  摘要：

  Copper complexes, [Cu(dm4bt)Cl(Hipht)] (1) and [(Cu(dm4bt)(H2O)(ipht)}(4)center dot 2H(2)O] (2) (where dm4bt is 2,2'-dimethy1-4,4'-bithiazole, Hipht is hydrogen isophthalate and ipht is isophthalate) have been synthesized. These two complexes were characterized by IR, UV-Vis and EPR spectroscopy. Moreover; their single-crystal structures were studied by the X-ray diffraction method. Complex 1 has a monomer structure and copper has accepted a distorted square pyramidal structure. Isophthalic acid in 1 lost one of its protons and produced one bidentate carboxylate and one free carboxylic acid. Controlled deprotonation in the presence of ethylene diamine results in self-assemblies of 1 to form a tetramer complex of 2. Complex 2 has two kinds of spatial isomers which are resolved by EPR and X-ray. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.05.007