| 253141-30-9

• CAS: 253141-30-9
• 化学式: C₃₄H₁₈Br₄ClCrN₂O₂
• 分子量: 893.594
• InChiKey: JNRPBVIKHRBTIC-HJDLTMEESA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  chromium dichloride 、 rac-N,N’-bis(3,5-dibromosalicylidene)-1,1’-binaphthyl-2,2’-diamine 在 air 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Asymmetric epoxidation catalyzed by Cr(III)-binaphthyl Schiff base complexes

  摘要：

  A series of chromic complexes with binaphthyl Schiff base as ligands are synthesized. Their catalytic abilities in asymmetric epoxidation and the effects of reaction conditions such as temperature, solvent and additive have also been studied. leading to the highest ee of 65% for 4-chlorostyrene; the reaction seems to involve a Cr(V)-oxo active species, (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.04.002