[Mo2Cp2{μ-κ1:η2-C(Ph)CO}(μ-PCy2)(CO)(κ1-N2CPh2)] | 1313211-16-3

• 英文名称: [Mo2Cp2{μ-κ1:η2-C(Ph)CO}(μ-PCy2)(CO)(κ1-N2CPh2)]
• 英文别名: [Mo₂Cp₂{μ-κ¹:η²-C(Ph)CO}(μ-PCy₂)(CO)(κ¹-N₂CPh₂)]；[Mo2(C5H5)2(μ-η1:η2-C(Ph)CO)(μ-PCy2)(CO)(κ1-N2CPh2)]
• CAS: 1313211-16-3
• 化学式: C₄₄H₄₇Mo₂N₂O₂P
• 分子量: 858.723
• InChiKey: SIWXIUDCJWITMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Mo2Cp2{μ-κ1:η2-C(Ph)CO}(μ-PCy2)(CO)(κ1-N2CPh2)] 以 甲苯 为溶剂， 生成 [Mo₂Cp₂(μ-CPh)(μ-PCy₂)(CO)(κ¹-N₂CPh₂)]
  参考文献：
  名称：

  Multisite Reactivity of the Central Mo₂CP Core in the Unsaturated Carbyne-Bridged Complex [Mo₂(η⁵-C₅H₅)₂(μ-CPh)(μ-PCy₂)(CO)₂]

  摘要：

  DOI：

  10.1021/om2003738
• 作为产物：
  描述：

  一氧化碳 、 [Mo₂Cp₂(μ-CPh)(μ-PCy₂)(CO)(κ¹-N₂CPh₂)] 以 二氯甲烷 为溶剂， 生成 [Mo2Cp2{μ-κ1:η2-C(Ph)CO}(μ-PCy2)(CO)(κ1-N2CPh2)]
  参考文献：
  名称：

  Multisite Reactivity of the Central Mo₂CP Core in the Unsaturated Carbyne-Bridged Complex [Mo₂(η⁵-C₅H₅)₂(μ-CPh)(μ-PCy₂)(CO)₂]

  摘要：

  DOI：

  10.1021/om2003738

文献信息

• C–C and C–N Couplings in Reactions of the Benzylidyne-Bridged Complex [Mo₂Cp₂(μ-CPh)(μ-PCy₂)(CO)₂] with Small Unsaturated Organics
  作者：M. Esther García、Daniel García-Vivó、Sonia Menéndez、Miguel A. Ruiz

  DOI：10.1021/acs.organomet.6b00552

  日期：2016.10.24

  The ability of the title compound to promote C-C coupling processes has been analyzed by examining its reactions with diazoalkanes, alkynes, and other unsaturated organic molecules. The title compound reacted with N2CPh2 at room temperature to give a mixture of ketenyl complex [Mo2Cp2mu-kappa(1):eta(2)-C(Ph)CO}(mu-PCy2)(CO)(kappa(1)-N2CPh2)] and carbyne complex [Mo2Cp2(mu-CPh)(mu-PCy2)(CO)(kappa(1)-N2CPh2)], products which can be converted into each other by addition/removal of CO, respectively. In contrast, denitrogenation took place rapidly in analogous reactions with diazomethane and benzylazide at room temperature, to yield, respectively, the corresponding alkenyl [Mo2Cp2mu-kappa(1):eta(2)-C(Ph)CH2} (mu-PCy2) (CO)(2)] and iminoacyl [Mo2Cp2mu-C(Ph)NCH2Ph}(mu-PCy2)(CO)(2)] derivatives, following from selective C-C and C-N couplings. The title compound reacted at 333 K with methyl propiolate to give the corresponding propenylylidene derivative [Mo2Cp2mu-kappa(2):eta(3)-CPhCHC(CO2Me)}(mu-PCy2)(CO)(2)], as a result of selective coupling of the carbyne ligand to the terminal carbon of the alkyne. A related complex could be obtained when using the internal alkyne dimethyl acetylenedicarboxylate.