(C6F5)2BCH2SPh(CH2CH2Ph)RuH(PPh3)2 | 1369525-28-9

• 英文名称: (C6F5)2BCH2SPh(CH2CH2Ph)RuH(PPh3)2
• CAS: 1369525-28-9
• 化学式: C₆₃H₄₇BF₁₀P₂RuS
• 分子量: 1199.94
• InChiKey: FPFMBFUFLARZEN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (C6F5)2BCH2SPh(CCPh)RuH(PPh3)2 、 氢气 以 苯 为溶剂， 以96%的产率得到(C6F5)2BCH2SPh(CH2CH2Ph)RuH(PPh3)2
  参考文献：
  名称：

  Ruthenium and Rhodium Complexes of Thioether-Alkynylborates

  摘要：

  The species ((C6F5)(2)BCH2SPh)(2) reacts with PhC CLi to give the thioether-alkynylborate (C6F5)(2)BCH2SPh(C CPh)Li(THF)(2) (1). Subsequent reaction with (Ph3P)(3)RuHCl, (Ph3P)(3)RhCl, and [(COD)Rh(mu-Cl)](2) gives (C6F5)(2)BCH2SPh(C CPh)RuH(PPh3)(2) (2), (C6F5)(2)BCH2SPh(C CPh)Rh(PPh3)(2) (4), and (C6F5)(2)BCH2SPh(C CPh)Rh(COD) (5), respectively, demonstrating a bidentate binding mode via the alkynyl and thioether donors of the borate. Subsequent reactions of 2 and 4 with H-2 gave (C6F5)(2)BCH2SPh(CH2CH2Ph)RuH(PPh3)(2) (3) and ((C6F5)(2)BCH2SPh(CHCHPh))Rh(PPh3)(2) (6). In the former case, the borate remains bound to the metal via a g-interaction with the thioether-arene ring, while in the latter case, S and alkene binding is observed.

  DOI：

  10.1021/om300075r