η(5)-(2,5-bis(tert-butyl)phospholyl)gallium | 233278-95-0

• 英文名称: η(5)-(2,5-bis(tert-butyl)phospholyl)gallium
• 英文别名: η(5)-2,5-di-(t-butyl)phospholylgallium(I)
• CAS: 233278-95-0
• 化学式: C₁₂H₂₀GaP
• 分子量: 264.988
• InChiKey: PETSUZBOUJSCPZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  五羰基(顺式环辛烯)铬 、 η(5)-(2,5-bis(tert-butyl)phospholyl)gallium 以 正己烷 为溶剂， 以80%的产率得到η(5)-(2,5-bis(tert-butyl)phospholyl)gallium(I) pentacarbonylchromium
  参考文献：
  名称：

  η5-Phospholylgallium: The First Monomeric Polyhapto Compound between a Phospholyl Ligand and a Main Group Metal

  摘要：

  Monomeric polyhapto-bound phospholyl compounds were hitherto unknown for the main group elements. Use of a solution of metastable GaBr has allowed the synthesis of monomeric η5 -phospholylgallium, which has been characterized by X-ray structure analysis as the Cr(CO)5 complex 1.

  DOI：

  10.1002/(sici)1521-3773(19990601)38:11<1646::aid-anie1646>3.0.co;2-z
• 作为产物：
  描述：

  gallium(I) bromide 、 lithium 2,5-bis(tert-butyl)phospholide 以 甲苯 为溶剂， 以70%的产率得到η(5)-(2,5-bis(tert-butyl)phospholyl)gallium
  参考文献：
  名称：

  η5-Phospholylgallium: The First Monomeric Polyhapto Compound between a Phospholyl Ligand and a Main Group Metal

  摘要：

  Monomeric polyhapto-bound phospholyl compounds were hitherto unknown for the main group elements. Use of a solution of metastable GaBr has allowed the synthesis of monomeric η5 -phospholylgallium, which has been characterized by X-ray structure analysis as the Cr(CO)5 complex 1.

  DOI：

  10.1002/(sici)1521-3773(19990601)38:11<1646::aid-anie1646>3.0.co;2-z