| 190252-82-5

• CAS: 190252-82-5
• 化学式: C₄₄H₈₈Ga₂P₂
• 分子量: 818.576
• InChiKey: MIDUDDCUSWMXJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dineopentylgalliumchloride 、 二环己基磷化锂 以 乙醚 为溶剂， 以84.4%的产率得到
  参考文献：
  名称：

  Cyclopentadiene Elimination Reaction as a Route to Bis(neopentyl)gallium Phosphides. Crystal and Molecular Structures of [(Me₃CCH₂)₂GaPEt₂]₂ and [(Me₃CCH₂)₂GaP(C₆H₁₁)₂]₂

  摘要：

  The compound (Me3CCH2)(2)Ga(C5H5) has been observed to react at room temperature in pentane solution with HPEt2 and H2P(C6H11) to eliminate C5H6 and form [(Me3CCH2)(2)-GaPEt2](2) and [(Me3CCH2)(2)GaP(H)(C6H11)](2), respectively. The additional new compound [(Me3CCH2)(2)GaP(C6H11)(2)](2) was prepared by a metathetical reaction between Ga(CH2CMe3)(2)-Cl and LiP(C6H11)(2) in diethyl ether. All three compounds were fully characterized in solution, whereas two of the three, [(Me3CCH2)(2)GaPEt2](2) and [(Me3CCH2)(2)GaP(C6H11)(2)](2), were characterized by X-ray structural studies.

  DOI：

  10.1021/om970090p