[Co3(3,5-dimethylpyrazol)2(glutarato(1-))2(glutarato(2-))2(methanol)4] | 1162659-32-6

• 英文名称: [Co3(3,5-dimethylpyrazol)2(glutarato(1-))2(glutarato(2-))2(methanol)4]
• CAS: 1162659-32-6
• 化学式: C₃₄H₅₈Co₃N₄O₂₀
• 分子量: 1019.83
• InChiKey: SLGZATJVJAKRAH-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡唑 、 甲醇 、 戊二酸 、 cobalt(II) diacetate tetrahydrate 以 甲醇 为溶剂， 以84.18%的产率得到[Co3(3,5-dimethylpyrazol)2(glutarato(1-))2(glutarato(2-))2(methanol)4]
  参考文献：
  名称：

  Constructions of a set of hydrogen-bonded supramolecules from reactions of transition metals with 3,5-dimethylpyrazole and different dicarboxylate ligands

  摘要：

  Three new supramolecular coordination complexes [Zn(Hdmpz)(2)(O2C(CH2)(2)CO2)](n) (1), Ni-3(Hdmpz)(4)-(HOOC(CH2)(2)CO2)(2)(O2C(CH2)(2)CO2)(2)(CH3OH)(2) (2) and Co-3(Hdmpz)(2)(HOOC(CH2)(3)CO2)(2)(O2C(CH2)(3)CO2)(2)-(CH3OH)(4) (3) (Hdmpz = 3,5-dimethylpyrazol) have been synthesized and characterized by elemental analyses, IR spectra and single crystal X-ray diffraction analysis. Complex 1 is a polymer with the ZnO4N2 core that is interconnected by bridging succinate moieties into a 1D chain structure. Complexes 2 and 3 are discrete structures, both of them have two types of bridging-coordinated modes of carboxylate ligands (mu(3)-eta(2)-eta(2), mu(2)-eta(1)-eta(1)). And there are rich intra- or intermolecular hydrogen bonds in the crystals of 1-3, thereby forming a set of supramolecular frameworks. In addition, the thermal behaviors of 1-3 were also investigated. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.12.022