ZrCl(N(iPr)P(iPr)2)3 | 1190919-95-9

• 英文名称: ZrCl(N(iPr)P(iPr)2)3
• CAS: 1190919-95-9
• 化学式: C₂₇H₆₃ClN₃P₃Zr
• 分子量: 649.416
• InChiKey: GGMPRUOQZFNMJR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ZrCl(N(iPr)P(iPr)2)3 在 air 作用下， 以 neat (no solvent) 为溶剂， 生成 ZrCl(N(iPr)P(iPr)2)2(N(iPr)PO(iPr)2)
  参考文献：
  名称：

  Multielectron Redox Activity Facilitated by Metal−Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands

  摘要：

  Linkage of a Lewis acidic early transition metal (Zr) and an electron-rich late transition metal (Co) using ambidentate phosphinoamide ligands leads to complexes featuring dative M-M interactions. By removing electron density from the Co center, these metal-metal interactions facilitate a two-electron reduction at cobalt at potentials 0.6-0.9 V more positive than in analogous monometallics.

  DOI：

  10.1021/ic900552b
• 作为产物：
  描述：

  氯化锆(IV) 、 i-PrNHP(i-Pr)2 在 CH₃CH₂CH₂CH₂Li 作用下， 以 乙醚 、 正己烷 为溶剂， 以32.7%的产率得到ZrCl(N(iPr)P(iPr)2)3
  参考文献：
  名称：

  Multielectron Redox Activity Facilitated by Metal−Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands

  摘要：

  Linkage of a Lewis acidic early transition metal (Zr) and an electron-rich late transition metal (Co) using ambidentate phosphinoamide ligands leads to complexes featuring dative M-M interactions. By removing electron density from the Co center, these metal-metal interactions facilitate a two-electron reduction at cobalt at potentials 0.6-0.9 V more positive than in analogous monometallics.

  DOI：

  10.1021/ic900552b