[([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(fluorobenzene)][B(C6F5)4] | 874919-67-2

• 英文名称: [([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(fluorobenzene)][B(C6F5)4]
• 英文别名: [(nacnac)Ti=N-2,6-(i)Pr2C6H3(fluorobenzene)][B(C6F5)4]
• CAS: 874919-67-2
• 化学式: C₂₄BF₂₀*C₅₃H₇₅FN₃Ti
• 分子量: 1500.12
• InChiKey: DWIKGIKSJSZAHW-IYVJWHKNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(fluorobenzene)][B(C6F5)4] 、 二苯基乙炔 以 not given 为溶剂， 以99%的产率得到[([2,6-(i)Pr₂C₆H₃NC((t)Bu)]2CH)TiN(2,6-(i)Pr₂C₆H₃)CPhCPh][B(C₆F₅)4]
  参考文献：
  名称：

  A Fluorobenzene Adduct of Ti(IV), and Catalytic Carboamination to Prepare α,β-Unsaturated Imines and Triaryl-Substituted Quinolines

  摘要：

  A rare fluorobenzene adduct of group 4, [(nacnac)Ti=NAr(FC6H5)][B(C6F5)4] (nacnac- = [ArNC(tBu)]2CH, Ar = 2,6-iPr2C6H3), has been isolated and structurally characterized. This highly electron-deficient system engages readily in imine metathesis and catalyzes carboamination reactions involving diphenylacetylene and aldimines to afford alpha,beta-unsaturated imines as well as triaryl-substituted quinolines. The latter product results from cyclization of the corresponding electron-rich alpha,beta-unsaturated imine.

  DOI：

  10.1021/ja0566026
• 作为产物：
  描述：

  氟苯 、 [([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(η1-C6H5NMe2)][B(C6F5)4] 以 氟苯 为溶剂， 生成 [([2,6-(i)Pr2C6H3NC((t)Bu)]2CH)Ti=N-2,6-(i)Pr2C6H3(fluorobenzene)][B(C6F5)4]
  参考文献：
  名称：

  A Fluorobenzene Adduct of Ti(IV), and Catalytic Carboamination to Prepare α,β-Unsaturated Imines and Triaryl-Substituted Quinolines

  摘要：

  A rare fluorobenzene adduct of group 4, [(nacnac)Ti=NAr(FC6H5)][B(C6F5)4] (nacnac- = [ArNC(tBu)]2CH, Ar = 2,6-iPr2C6H3), has been isolated and structurally characterized. This highly electron-deficient system engages readily in imine metathesis and catalyzes carboamination reactions involving diphenylacetylene and aldimines to afford alpha,beta-unsaturated imines as well as triaryl-substituted quinolines. The latter product results from cyclization of the corresponding electron-rich alpha,beta-unsaturated imine.

  DOI：

  10.1021/ja0566026