DAB-dend-(N=CH(η5-C5(CH3)4)Fe(η5-C5(CH3)4H))4 | 938083-07-9

• 英文名称: DAB-dend-(N=CH(η5-C5(CH3)4)Fe(η5-C5(CH3)4H))4
• CAS: 938083-07-9
• 化学式: C₉₂H₁₃₆Fe₄N₆
• 分子量: 1549.52
• InChiKey: CABUZCCOQZQSHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  DAB-dend-(N=CH(η5-C5(CH3)4)Fe(η5-C5(CH3)4H))4 、 sodium tetrahydroborate 在 水 作用下， 以 四氢呋喃 为溶剂， 生成 DAB-dend-(NHCH2(η5-C5(CH3)4)Fe(η5-C5(CH3)4H))4
  参考文献：
  名称：

  Synthesis and Electrochemistry of Octamethylferrocenyl-Functionalized Dendrimers

  摘要：

  New octamethylferrocenyl dendritic macromolecules are reported. The condensation reaction of octamethylferrocenyl aldehyde (1) with dendritic polyamines DAB-dend-(NH2)(x) (x = 4, 8, 16, 32) affords up to the fourth generation of the octamethylferrocenylimine dendrimers DAB-dend-(NCHFc(#))(x) (x = 4, 8, 16, 32) (2-5). Reduction of the imine groups leads to the corresponding octamethylferrocenylmethylamine dendrimers DAB-dend-(NHCH(2)Fc(#))(x) (6-9) with 4, 8, 16, and 32 octamethylferrocenyl units per molecule, respectively. Characterization of the synthesized dendrimers by H-1 and C-13{H-1} NMR and IR spectroscopy, mass spectrometry, and elemental analysis supports their assigned structures. The redox activity of the octamethylferrocenyl centers in 6-9 has been characterized by cyclic voltammetry. Solution electrochemical studies showed that all the octamethylferrocenyl redox centers attached to the dendritic surface are electrochemically independent and that, in CH2Cl2 as solvent, the neutral dendrimers undergo oxidative precipitation onto the electrode surfaces.

  DOI：

  10.1021/om070070f
• 作为产物：
  描述：

  1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene 、 N,N,N,N-四(3-氨基丙基)-1,4-丁二胺 以 苯 为溶剂， 生成 DAB-dend-(N=CH(η5-C5(CH3)4)Fe(η5-C5(CH3)4H))4
  参考文献：
  名称：

  Synthesis and Electrochemistry of Octamethylferrocenyl-Functionalized Dendrimers

  摘要：

  New octamethylferrocenyl dendritic macromolecules are reported. The condensation reaction of octamethylferrocenyl aldehyde (1) with dendritic polyamines DAB-dend-(NH2)(x) (x = 4, 8, 16, 32) affords up to the fourth generation of the octamethylferrocenylimine dendrimers DAB-dend-(NCHFc(#))(x) (x = 4, 8, 16, 32) (2-5). Reduction of the imine groups leads to the corresponding octamethylferrocenylmethylamine dendrimers DAB-dend-(NHCH(2)Fc(#))(x) (6-9) with 4, 8, 16, and 32 octamethylferrocenyl units per molecule, respectively. Characterization of the synthesized dendrimers by H-1 and C-13{H-1} NMR and IR spectroscopy, mass spectrometry, and elemental analysis supports their assigned structures. The redox activity of the octamethylferrocenyl centers in 6-9 has been characterized by cyclic voltammetry. Solution electrochemical studies showed that all the octamethylferrocenyl redox centers attached to the dendritic surface are electrochemically independent and that, in CH2Cl2 as solvent, the neutral dendrimers undergo oxidative precipitation onto the electrode surfaces.

  DOI：

  10.1021/om070070f